Anatase nanotubes as an electrode material for Lithium-Ion batteries
Anatase TiO2 nanotubes were synthesized via the hydrothermal method followed by annealing at 500 °C in argon for 1 h. The phase structure, morphology, and composition were investigated in detail by means of X-ray diffraction, scanning and high-resolution transmission electron microscopy, infrared sp...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
April 2, 2012
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| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2012, Jahrgang: 116, Heft: 15, Pages: 8714-8720 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/jp300955r |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1021/jp300955r Verlag, Volltext: https://doi.org/10.1021/jp300955r 
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| Verfasserangaben: | G.S. Zakharova, C. Jähne, A. Popa, Ch. Täschner, Th. Gemming, A. Leonhardt, B. Büchner, and R. Klingeler |
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| 520 | |a Anatase TiO2 nanotubes were synthesized via the hydrothermal method followed by annealing at 500 °C in argon for 1 h. The phase structure, morphology, and composition were investigated in detail by means of X-ray diffraction, scanning and high-resolution transmission electron microscopy, infrared spectroscopy, and thermal analysis. The material consists of nanotubes with diameter of 10-15 nm and lengths of several hundred nanometers. The electrochemical properties were investigated by cyclic voltammetry and galvanostatic cycling. The data imply a first cycle irreversible capacity of 385 mAh/g, and capacities of 307 and 265 mAh/g after the second and 50th cycle, respectively, at C/10. The Coulombic efficiency of about 99% after cycle 50 implies excellent cycling stability. Hence anatase TiO2 nanotubes evidence great potential for usage in high-power lithium-ion batteries. | ||
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