The first triple-decker complex with a carbenium center, (CpCo([mu]-C3B2Me5)RuC5Me4CH2)+: synthesis, reactivity, X-ray structure, and bonding
The first derivative of the methylium cation with the triple-decker substituent, [CpCo(C3B2Me5)RuC5Me4CH2]PF6 (2PF6), was synthesized from the reaction of the triple-decker complex CpCo(C3B2Me5)RuCp* (1) with the salt of the trityl cation [CPh3]+. The X-ray crystal structure of 2PF6 reveals that the...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
03 July 2017
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| In: |
Chemistry - a European journal
Year: 2017, Jahrgang: 23, Heft: 49, Pages: 11935-11944 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201702571 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201702571 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201702571 
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| Verfasserangaben: | Dmitry V. Muratov, Alexander S. Romanov, Maddalena Corsini, Alexander R. Kudinov, Fabrizia Fabrizi de Biani, and Walter Siebert |
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| 245 | 1 | 4 | |a The first triple-decker complex with a carbenium center, (CpCo([mu]-C3B2Me5)RuC5Me4CH2)+ |b synthesis, reactivity, X-ray structure, and bonding |c Dmitry V. Muratov, Alexander S. Romanov, Maddalena Corsini, Alexander R. Kudinov, Fabrizia Fabrizi de Biani, and Walter Siebert |
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| 246 | 3 | 3 | |a The first triple-decker complex with a carbenium center, (CpCo ([mu]-C 3 B 2 Me 5)RuC 5 Me 4 CH 2) + |
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| 520 | |a The first derivative of the methylium cation with the triple-decker substituent, [CpCo(C3B2Me5)RuC5Me4CH2]PF6 (2PF6), was synthesized from the reaction of the triple-decker complex CpCo(C3B2Me5)RuCp* (1) with the salt of the trityl cation [CPh3]+. The X-ray crystal structure of 2PF6 reveals that the methylium carbon is bound to the ruthenium with Ru−C bond length of 2.259 Å and corresponds to the description of its structure as η6-fulvene-ruthenium. Reactions of 2PF6 with nucleophiles OH−, Ph3P, Et3N led to the corresponding derivatives of 1 in high yields. Aromatic amines PhNEt2 and 4-MeC6H4NH2 react with 2PF6 to give the electrophilic aromatic substitution products quantitatively. Chemical reduction of 2PF6 with Zn powder in tetrahydrofuran leads to the formation of the bis(triple-decker) derivative (CpCo(C3B2Me5)RuC5Me4CH2)2 (10) with a CH2CH2-bridge. The structures of complexes 4, 7-10 were determined by X-ray diffraction. Density functional calculations support the crystallographically determined geometry of 2 and allow rationalization of some characteristics of its structure, spectroscopy, and reactivity. | ||
| 650 | 4 | |a boron | |
| 650 | 4 | |a cobalt | |
| 650 | 4 | |a electrochemistry | |
| 650 | 4 | |a ruthenium | |
| 650 | 4 | |a sandwich compound | |
| 650 | 4 | |a triple-decker complex | |
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