Pitfalls and limitations in Group 6 triamidophosphane chemistry: cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formation
The benzylene-linked triaminophosphanes P(C6H4-o-CH2NHXyl)3 ([A]H3) and P(CH2C6H4-o-NHPh)3 ([B]H3) react with (Me2N)3Mo≡N to afford the square-pyramidal nitrido complexes 1 and 2, each comprising one residual dimethylamido moiety and one uncoordinated ligand sidearm. Only the [A]-coordinated complex...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2017
|
| In: |
European journal of inorganic chemistry
Year: 2017, Heft: 46, Pages: 5442-5450 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201701023 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201701023 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701023 
|
| Verfasserangaben: | Malte Sietzen, Sonja Batke, Lukas Merz, Hubert Wadepohl, and Joachim Ballmann |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1580486622 | ||
| 003 | DE-627 | ||
| 005 | 20230427065702.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180829s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/ejic.201701023 |2 doi | |
| 035 | |a (DE-627)1580486622 | ||
| 035 | |a (DE-576)510486622 | ||
| 035 | |a (DE-599)BSZ510486622 | ||
| 035 | |a (OCoLC)1341017805 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Sietzen, Malte |e VerfasserIn |0 (DE-588)1115826816 |0 (DE-627)870061852 |0 (DE-576)477963064 |4 aut | |
| 245 | 1 | 0 | |a Pitfalls and limitations in Group 6 triamidophosphane chemistry |b cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formation |c Malte Sietzen, Sonja Batke, Lukas Merz, Hubert Wadepohl, and Joachim Ballmann |
| 246 | 3 | 0 | |a λ lambda |
| 264 | 1 | |c 2017 | |
| 300 | |a 9 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Zusatz zum Titel ist „5“ nach [lambda] hochgestellt | ||
| 500 | |a Gesehen am 29.08.2018 | ||
| 520 | |a The benzylene-linked triaminophosphanes P(C6H4-o-CH2NHXyl)3 ([A]H3) and P(CH2C6H4-o-NHPh)3 ([B]H3) react with (Me2N)3Mo≡N to afford the square-pyramidal nitrido complexes 1 and 2, each comprising one residual dimethylamido moiety and one uncoordinated ligand sidearm. Only the [A]-coordinated complex 1 was found to eliminate the remaining dimethylamido ligand on heating. Instead of the closed-cage molybdenum(VI) nitrido complex [A]Mo≡N, cyclometalated molybdaziridine 3 was isolated, as the syn alignment of the uncoordinated sidearm and nitrido ligand in 1 inhibits a productive cage-closure reaction. By using [NPN]-coordinated model complexes, analogous syn arrangements were found not only for molybdenum, but also for the related tungsten nitrido complexes and the group 5 imides. Attempts to access the closed-cage MoVI nitrido comlex [A]Mo≡N by transmetalation between [A]Sn(nBu) (9) and (tBuO)3Mo≡N led to the formation of spiro-[4.4]-λ5-amidophosphorane 10. These results contrast with the findings made for azatranes and methylene-linked exo-P-configured triamidophosphane complexes. | ||
| 650 | 4 | |a Molybdenum | |
| 650 | 4 | |a N | |
| 650 | 4 | |a Nitrido complexes | |
| 650 | 4 | |a P ligands | |
| 650 | 4 | |a Spiro compounds | |
| 650 | 4 | |a Tripodal ligands | |
| 700 | 1 | |a Batke, Sonja |e VerfasserIn |0 (DE-588)1151830062 |0 (DE-627)101233953X |0 (DE-576)49807840X |4 aut | |
| 700 | 1 | |a Merz, Lukas |e VerfasserIn |0 (DE-588)1165663635 |0 (DE-627)1029733449 |0 (DE-576)510486436 |4 aut | |
| 700 | 1 | |a Wadepohl, Hubert |e VerfasserIn |0 (DE-588)1019812354 |0 (DE-627)691026572 |0 (DE-576)358886724 |4 aut | |
| 700 | 1 | |a Ballmann, Joachim |d 1979-2025 |e VerfasserIn |0 (DE-588)137662866 |0 (DE-627)594828848 |0 (DE-576)304830542 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t European journal of inorganic chemistry |d Weinheim : Wiley-VCH, 1998 |g (2017), 46, Seite 5442-5450 |h Online-Ressource |w (DE-627)269534520 |w (DE-600)1475009-0 |w (DE-576)077884671 |x 1099-0682 |7 nnas |a Pitfalls and limitations in Group 6 triamidophosphane chemistry cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formation |
| 773 | 1 | 8 | |g year:2017 |g number:46 |g pages:5442-5450 |g extent:9 |a Pitfalls and limitations in Group 6 triamidophosphane chemistry cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formation |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1002/ejic.201701023 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701023 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180829 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 137662866 |a Ballmann, Joachim |m 137662866:Ballmann, Joachim |d 120000 |d 120200 |e 120000PB137662866 |e 120200PB137662866 |k 0/120000/ |k 1/120000/120200/ |p 5 |y j | ||
| 998 | |g 1019812354 |a Wadepohl, Hubert |m 1019812354:Wadepohl, Hubert |d 120000 |d 120200 |e 120000PW1019812354 |e 120200PW1019812354 |k 0/120000/ |k 1/120000/120200/ |p 4 | ||
| 998 | |g 1165663635 |a Merz, Lukas |m 1165663635:Merz, Lukas |d 120000 |d 120200 |e 120000PM1165663635 |e 120200PM1165663635 |k 0/120000/ |k 1/120000/120200/ |p 3 | ||
| 998 | |g 1151830062 |a Batke, Sonja |m 1151830062:Batke, Sonja |d 120000 |d 120200 |e 120000PB1151830062 |e 120200PB1151830062 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 998 | |g 1115826816 |a Sietzen, Malte |m 1115826816:Sietzen, Malte |p 1 |x j | ||
| 999 | |a KXP-PPN1580486622 |e 3024100784 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"origin":[{"dateIssuedDisp":"2017","dateIssuedKey":"2017"}],"note":["Im Zusatz zum Titel ist „5“ nach [lambda] hochgestellt","Gesehen am 29.08.2018"],"recId":"1580486622","relHost":[{"id":{"doi":["10.1002/(ISSN)1099-0682c"],"issn":["1099-0682"],"eki":["269534520"],"zdb":["1475009-0"]},"language":["eng"],"recId":"269534520","origin":[{"publisher":"Wiley-VCH","dateIssuedDisp":"1998-","dateIssuedKey":"1998","publisherPlace":"Weinheim"}],"note":["Gesehen am 27.02.24","Fortsetzung der Druck-Ausgabe"],"pubHistory":["Volume 1998, Issue 1 (January 1998)-"],"part":{"pages":"5442-5450","year":"2017","text":"(2017), 46, Seite 5442-5450","extent":"9","issue":"46"},"title":[{"title_sort":"European journal of inorganic chemistry","title":"European journal of inorganic chemistry"}],"disp":"Pitfalls and limitations in Group 6 triamidophosphane chemistry cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formationEuropean journal of inorganic chemistry","physDesc":[{"extent":"Online-Ressource"}],"type":{"bibl":"periodical","media":"Online-Ressource"}}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"language":["eng"],"name":{"displayForm":["Malte Sietzen, Sonja Batke, Lukas Merz, Hubert Wadepohl, and Joachim Ballmann"]},"person":[{"given":"Malte","display":"Sietzen, Malte","role":"aut","family":"Sietzen"},{"display":"Batke, Sonja","given":"Sonja","role":"aut","family":"Batke"},{"role":"aut","given":"Lukas","display":"Merz, Lukas","family":"Merz"},{"family":"Wadepohl","role":"aut","display":"Wadepohl, Hubert","given":"Hubert"},{"role":"aut","given":"Joachim","display":"Ballmann, Joachim","family":"Ballmann"}],"title":[{"subtitle":"cage-closure restrictions in square-pyramidal nitrido complexes and degradation via spiro-[4.4]-[lambda]5-amidophosphorane formation","title_sort":"Pitfalls and limitations in Group 6 triamidophosphane chemistry","title":"Pitfalls and limitations in Group 6 triamidophosphane chemistry"}],"id":{"doi":["10.1002/ejic.201701023"],"eki":["1580486622"]},"physDesc":[{"extent":"9 S."}]} | ||
| SRT | |a SIETZENMALPITFALLSAN2017 | ||