Fire and ice: a gold(III) monohydride
Good as gold: Gold hydrides were long considered unstable. In the past few years reports have appeared on not only the stable NHC gold(I) monohydride complex 1 (see structure; NHC=N-heterocyclic carbene) but also a dinuclear gold(I) hydride and most recently the gold(III) monohydride complex 2 with...
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| 1. Verfasser: | |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 26, 2012
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| In: |
Angewandte Chemie. International edition
Year: 2012, Jahrgang: 51, Heft: 52, Pages: 12935-12936 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201208603 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201208603 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201208603 
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| Verfasserangaben: | A. Stephen K. Hashmi |
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| 520 | |a Good as gold: Gold hydrides were long considered unstable. In the past few years reports have appeared on not only the stable NHC gold(I) monohydride complex 1 (see structure; NHC=N-heterocyclic carbene) but also a dinuclear gold(I) hydride and most recently the gold(III) monohydride complex 2 with a C-N-C pincer ligand. One can expect new and important impulses for inorganic and organometallic chemistry and homogeneous gold catalysis. | ||
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