Simple gold-catalyzed synthesis of benzofulvenes: gem-diaurated species as “Instant dual-activation” precatalysts
Alkyl-substituted diynes deliver benzofulvenes in a unique gold-catalyzed reaction. The catalytic cycle involves the formation of gold acetylides by alkynyl C-H activation, the formation of vinylidene gold(I) intermediates by dual activation, and alkyl C-H activation by the vinylidene gold(I) specie...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 19, 2012
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| In: |
Angewandte Chemie. International edition
Year: 2012, Jahrgang: 51, Heft: 18, Pages: 4456-4460 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201109183 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201109183 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201109183 
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| Verfasserangaben: | A. Stephen K. Hashmi, Ingo Braun, Pascal Nösel, Johannes Schädlich, Marcel Wieteck, Matthias Rudolph, and Frank Rominger |
| Zusammenfassung: | Alkyl-substituted diynes deliver benzofulvenes in a unique gold-catalyzed reaction. The catalytic cycle involves the formation of gold acetylides by alkynyl C-H activation, the formation of vinylidene gold(I) intermediates by dual activation, and alkyl C-H activation by the vinylidene gold(I) species. gem-Diaurated species obtained from the catalysis reactions prove to be highly active catalysts for these conversions. |
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| Beschreibung: | Gesehen am 04.09.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201109183 |