A highly diastereoselective recognition process as the basis for the resolution of palladatricyclo[4.1.0.0 2,4]heptanes
The synthesis of palladatricyclo[4.1.0.02,4]heptane diastereomers by positional selective transesterification with (1R,2S,5R)(−)-menthol is used for the resolution of these chiral organometallic compounds. The separation process of the two diastereomers is simplified by an unprecedented aggregation...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 9, 2012
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| In: |
Organometallics
Year: 2012, Volume: 31, Issue: 2, Pages: 523-526 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om2009952 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/om2009952 Verlag, Volltext: http://pubs.acs.org/doi/10.1021/om2009952 
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| Author Notes: | A. Stephen K. Hashmi, Marc A. Grundl, Dominic Riedel, Matthias Rudolph, and Jan W. Bats |