Gold catalysis: non-spirocyclic intermediates in the conversion of furanynes by the formal insertion of an alkyne into an aryl-alkyl CC single bond
It takes al-kynes: The formation of furyl-substituted heterocycles from furanynes with donor groups on the furan-alkyne tether and mechanistic control experiments indicate the involvement of open-chained carbenium ions in the overall insertion of an alkyne into a CC bond, rather than the usual spir...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
16 July 2012
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| In: |
Chemistry - a European journal
Year: 2012, Jahrgang: 18, Heft: 34, Pages: 10480-10486 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201200306 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201200306 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201200306 
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| Verfasserangaben: | A. Stephen K. Hashmi, Tobias Häffner, Weibo Yang, Sreekumar Pankajakshan, Sascha Schäfer, Lara Schultes, Frank Rominger, and Wolfgang Frey |
| Zusammenfassung: | It takes al-kynes: The formation of furyl-substituted heterocycles from furanynes with donor groups on the furan-alkyne tether and mechanistic control experiments indicate the involvement of open-chained carbenium ions in the overall insertion of an alkyne into a CC bond, rather than the usual spirocyclic intermediates (see scheme). |
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| Beschreibung: | Gesehen am 06.09.2018 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201200306 |