Regioselective formation of saturated abnormal NHC-Gold(I) complexes by [3+2] cycloaddition of azomethine ylides and isonitrile gold(I) complexes
Abnormally easy: The first saturated abnormal NHC-gold(I) complexes are synthesized in a two-step procedure from commercially available gold(I) precursors. The reaction of gold-coordinated isonitriles with in situ generated azomethine ylides circumvents regioselectivity problems during the carbene f...
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| Main Authors: | , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
29 February 2012
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| In: |
Chemistry - a European journal
Year: 2012, Volume: 18, Issue: 13, Pages: 3827-3830 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201200217 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201200217 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201200217 |
| Author Notes: | A. Stephen K. Hashmi, Dominic Riedel, Matthias Rudolph, Frank Rominger, and Thomas Oeser |