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Gold-catalysis: highly efficient and regio-selective carbonyl migration in alkynyl-substituted indole-3-carboxamides leading to azepino[3,4-b]indol-1-ones

An unprecedented rearrangement/anellation sequence allows the clean synthesis of azepino[3,4-b]indol-1-ones from readily available starting materials. Alkyne-substituted indole-3-carboxamides were prepared and converted to azepino[3,4-b]indol-1-ones by the SPhosAuNTf2 catalyst (SPhos=2-dicyclohexylp...

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Hauptverfasser: Hashmi, A. Stephen K. (VerfasserIn) , Yang, Weibo (VerfasserIn) , Rominger, Frank (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: April 24, 2012
In: Advanced synthesis & catalysis
Year: 2012, Jahrgang: 354, Heft: 7, Pages: 1273-1279
ISSN:1615-4169
DOI:10.1002/adsc.201200092
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1002/adsc.201200092
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201200092
Volltext
Verfasserangaben:A. Stephen K. Hashmi, Weibo Yang, and Frank Rominger

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