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Cluster (Co3(CO)3([mu]2-CO)3([mu]3-C8H8))- as a ligand: xxperimental and theoretical study

The cluster anion [Co3(CO)3(µ2-CO)3(µ3-C8H8)]- (2) reacts with fragments [(ring)M]+ and [(cod)M]+ to give the Co3M clusters (ring)MCo3(CO)3(µ3-CO)3(µ3-C8H8) (ring)M = CpFe (3a), Cp*Fe (3b), CpRu (4a), (C4Me4)Co (5) and (cod)MCo3(CO)3(µ3-CO)3(µ3-C8H8) M = Rh (6), Ir (7), respectively. However, 2 does...

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Bibliographische Detailangaben
Hauptverfasser: Vinogradov, Mikhail M. (VerfasserIn) , Wadepohl, Hubert (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 08 November 2017
In: European journal of inorganic chemistry
Year: 2017, Heft: 48, Pages: 5663-5669
ISSN:1099-0682
DOI:10.1002/ejic.201701160
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201701160
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701160
Volltext
Verfasserangaben:Mikhail M. Vinogradov, Dmitry S. Perekalin, Evgenii I. Gutsul, Valentin V. Novikov, Alexander F. Smol'yakov, Hubert Wadepohl, Alexander R. Kudinov, Dmitry A. Loginov
Beschreibung
Zusammenfassung:The cluster anion [Co3(CO)3(µ2-CO)3(µ3-C8H8)]- (2) reacts with fragments [(ring)M]+ and [(cod)M]+ to give the Co3M clusters (ring)MCo3(CO)3(µ3-CO)3(µ3-C8H8) (ring)M = CpFe (3a), Cp*Fe (3b), CpRu (4a), (C4Me4)Co (5) and (cod)MCo3(CO)3(µ3-CO)3(µ3-C8H8) M = Rh (6), Ir (7), respectively. However, 2 does not form stable complexes with [(Ph3P)M]+ species (M = Cu, Ag, Au), which was explained on the basis of DFT calculations by the inefficient overlap between the cluster and fragment orbitals. The structures of 3b and 5 were determined by X-ray diffraction.
Beschreibung:Gesehen am 11.09.2018
Die komplette Formel im Titel steht in eckigen Klammern, die Zahlen sind tiefgestellt, der Bindestrich am Ende ist hochgestellt
Beschreibung:Online Resource
ISSN:1099-0682
DOI:10.1002/ejic.201701160

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