Cluster (Co3(CO)3([mu]2-CO)3([mu]3-C8H8))- as a ligand: xxperimental and theoretical study
The cluster anion [Co3(CO)3(µ2-CO)3(µ3-C8H8)]- (2) reacts with fragments [(ring)M]+ and [(cod)M]+ to give the Co3M clusters (ring)MCo3(CO)3(µ3-CO)3(µ3-C8H8) (ring)M = CpFe (3a), Cp*Fe (3b), CpRu (4a), (C4Me4)Co (5) and (cod)MCo3(CO)3(µ3-CO)3(µ3-C8H8) M = Rh (6), Ir (7), respectively. However, 2 does...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
08 November 2017
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| In: |
European journal of inorganic chemistry
Year: 2017, Heft: 48, Pages: 5663-5669 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201701160 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201701160 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701160 
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| Verfasserangaben: | Mikhail M. Vinogradov, Dmitry S. Perekalin, Evgenii I. Gutsul, Valentin V. Novikov, Alexander F. Smol'yakov, Hubert Wadepohl, Alexander R. Kudinov, Dmitry A. Loginov |
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| 245 | 1 | 0 | |a Cluster (Co3(CO)3([mu]2-CO)3([mu]3-C8H8))- as a ligand |b xxperimental and theoretical study |c Mikhail M. Vinogradov, Dmitry S. Perekalin, Evgenii I. Gutsul, Valentin V. Novikov, Alexander F. Smol'yakov, Hubert Wadepohl, Alexander R. Kudinov, Dmitry A. Loginov |
| 246 | 3 | 0 | |a Co3(CO)3(µ2-CO)3(µ3-C8H8) Co3(CO)3(my2-CO)3([my]3-C8H8 |
| 246 | 3 | 3 | |a Cluster (Co 3 (CO) 3 ([mu] 2-CO) 3 ([mu] 3 -C 8 H 8))- as a ligand |
| 264 | 1 | |c 08 November 2017 | |
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| 500 | |a Die komplette Formel im Titel steht in eckigen Klammern, die Zahlen sind tiefgestellt, der Bindestrich am Ende ist hochgestellt | ||
| 520 | |a The cluster anion [Co3(CO)3(µ2-CO)3(µ3-C8H8)]- (2) reacts with fragments [(ring)M]+ and [(cod)M]+ to give the Co3M clusters (ring)MCo3(CO)3(µ3-CO)3(µ3-C8H8) (ring)M = CpFe (3a), Cp*Fe (3b), CpRu (4a), (C4Me4)Co (5) and (cod)MCo3(CO)3(µ3-CO)3(µ3-C8H8) M = Rh (6), Ir (7), respectively. However, 2 does not form stable complexes with [(Ph3P)M]+ species (M = Cu, Ag, Au), which was explained on the basis of DFT calculations by the inefficient overlap between the cluster and fragment orbitals. The structures of 3b and 5 were determined by X-ray diffraction. | ||
| 650 | 4 | |a Anions | |
| 650 | 4 | |a Clusters | |
| 650 | 4 | |a Cobalt | |
| 650 | 4 | |a Density functional theory calculations | |
| 650 | 4 | |a Metal-metal interactions | |
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