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Transforming a chemically labile (2+3) imine cage into a robust carbamate cage

The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 °C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid (pH = −1) at room temperature without decomposition.

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Bibliographic Details
Main Authors: Hu, Xin-Yue (Author) , Zhang, Wen-Shan (Author) , Rominger, Frank (Author) , Wacker, Irene (Author) , Schröder, Rasmus R. (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 07 Jul 2017
In: Chemical communications
Year: 2017, Volume: 53, Issue: 61, Pages: 8616-8619
ISSN:1364-548X
DOI:10.1039/C7CC03677A
Online Access:Verlag, Volltext: http://dx.doi.org/10.1039/C7CC03677A
Verlag, Volltext: https://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc03677a
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Author Notes:Xin-Yue Hu, Wen-Shan Zhang, Frank Rominger, Irene Wacker, Rasmus R. Schröder, Michael Mastalerz
Description
Summary:The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 °C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid (pH = −1) at room temperature without decomposition.
Item Description:Gesehen am 12.09.2018
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C7CC03677A

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