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Cobalt alkyl complexes of a new family of chiral 1,3-Bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation

Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hyd...

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Hauptverfasser: Sauer, Désirée C. (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Gade, Lutz H. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: November 12, 2012
In: Inorganic chemistry
Year: 2012, Jahrgang: 51, Heft: 23, Pages: 12948-12958
ISSN:1520-510X
DOI:10.1021/ic3020749
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1021/ic3020749
Volltext
Verfasserangaben:Désirée C. Sauer, Hubert Wadepohl, and Lutz H. Gade
Beschreibung
Zusammenfassung:Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hydrosilylation of ketones was tested giving the corresponding alcohols in high yields and enantioselectivity.
Beschreibung:Gesehen am 13.09.2018
Beschreibung:Online Resource
ISSN:1520-510X
DOI:10.1021/ic3020749

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