Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface: a GISAXS study
The shape and size of self-assembled mesoscopic surface domains of fluorocarbon-hydrocarbon (FnHm) diblocks and the lateral correlation between these domains were quantitatively determined from grazing incidence small-angle X-ray scattering (GISAXS). The full calculation of structure and form factor...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
12 May 2017
|
| In: |
ChemPhysChem
Year: 2017, Volume: 18, Issue: 19, Pages: 2791-2798 |
| ISSN: | 1439-7641 |
| DOI: | 10.1002/cphc.201700325 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/cphc.201700325 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201700325 
|
| Author Notes: | Mariam Veschgini, Wasim Abuillan, Shigeto Inoue, Akihisa Yamamoto, Salomé Mielke, Xianhe Liu, Oleg Konovalov, Marie Pierre Krafft, and Motomu Tanaka |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1581153945 | ||
| 003 | DE-627 | ||
| 005 | 20220815014235.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180920s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/cphc.201700325 |2 doi | |
| 035 | |a (DE-627)1581153945 | ||
| 035 | |a (DE-576)511153945 | ||
| 035 | |a (DE-599)BSZ511153945 | ||
| 035 | |a (OCoLC)1341018826 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Veschgini, Mariam |e VerfasserIn |0 (DE-588)1124266933 |0 (DE-627)877979871 |0 (DE-576)482418575 |4 aut | |
| 245 | 1 | 0 | |a Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface |b a GISAXS study |c Mariam Veschgini, Wasim Abuillan, Shigeto Inoue, Akihisa Yamamoto, Salomé Mielke, Xianhe Liu, Oleg Konovalov, Marie Pierre Krafft, and Motomu Tanaka |
| 264 | 1 | |c 12 May 2017 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 20.09.2018 | ||
| 520 | |a The shape and size of self-assembled mesoscopic surface domains of fluorocarbon-hydrocarbon (FnHm) diblocks and the lateral correlation between these domains were quantitatively determined from grazing incidence small-angle X-ray scattering (GISAXS). The full calculation of structure and form factors unravels the influence of fluorocarbon and hydrocarbon block lengths on the diameter and height of the domains, and provides the inter-domain correlation length. The diameter of the domains, as determined from the form factor analysis, exhibits a monotonic increase in response to the systematic lengthening of each block, which can be attributed to the increase in van der Waals attraction between molecules. The pair correlation function in real space calculated from the structure factor implies that the inter-domain correlation can reach a distance that is over 25 times larger than the domain's size. The full calculation of the GISAXS signals introduced here opens a potential towards the hierarchical design of mesoscale domains of self-assembled small organic molecules, covering several orders of magnitude in space. | ||
| 650 | 4 | |a air/water interface | |
| 650 | 4 | |a GISAXS | |
| 650 | 4 | |a hierarchical self-assembly | |
| 650 | 4 | |a nano-domains | |
| 650 | 4 | |a semi-fluorinated alkanes | |
| 700 | 1 | |a Abuillan, Wasim |e VerfasserIn |0 (DE-588)1045296422 |0 (DE-627)774059095 |0 (DE-576)398923795 |4 aut | |
| 700 | 1 | |a Inoue, Shigeto |e VerfasserIn |0 (DE-588)1167448812 |0 (DE-627)1031121080 |0 (DE-576)51115304X |4 aut | |
| 700 | 1 | |a Mielke, Salomé |d 1991- |e VerfasserIn |0 (DE-588)1167448715 |0 (DE-627)1031605118 |0 (DE-576)511152620 |4 aut | |
| 700 | 1 | |a Tanaka, Motomu |e VerfasserIn |0 (DE-588)1060648377 |0 (DE-627)800414829 |0 (DE-576)416774636 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t ChemPhysChem |d Weinheim : Wiley-VCH Verl., 2000 |g 18(2017), 19, Seite 2791-2798 |h Online-Ressource |w (DE-627)320642216 |w (DE-600)2025223-7 |w (DE-576)091208599 |x 1439-7641 |7 nnas |a Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface a GISAXS study |
| 773 | 1 | 8 | |g volume:18 |g year:2017 |g number:19 |g pages:2791-2798 |g extent:8 |a Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface a GISAXS study |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1002/cphc.201700325 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201700325 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20180920 | ||
| 993 | |a Article | ||
| 994 | |a 2017 | ||
| 998 | |g 1060648377 |a Tanaka, Motomu |m 1060648377:Tanaka, Motomu |d 120000 |d 120300 |d 700000 |d 718000 |e 120000PT1060648377 |e 120300PT1060648377 |e 700000PT1060648377 |e 718000PT1060648377 |k 0/120000/ |k 1/120000/120300/ |k 0/700000/ |k 1/700000/718000/ |p 9 |y j | ||
| 998 | |g 1167448715 |a Mielke, Salomé |m 1167448715:Mielke, Salomé |d 120000 |d 120300 |e 120000PM1167448715 |e 120300PM1167448715 |k 0/120000/ |k 1/120000/120300/ |p 5 | ||
| 998 | |g 1167448812 |a Inoue, Shigeto |m 1167448812:Inoue, Shigeto |d 120000 |d 120300 |e 120000PI1167448812 |e 120300PI1167448812 |k 0/120000/ |k 1/120000/120300/ |p 3 | ||
| 998 | |g 1045296422 |a Abuillan, Wasim |m 1045296422:Abuillan, Wasim |d 120000 |d 120300 |e 120000PA1045296422 |e 120300PA1045296422 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 998 | |g 1124266933 |a Veschgini, Mariam |m 1124266933:Veschgini, Mariam |d 120000 |d 120300 |e 120000PV1124266933 |e 120300PV1124266933 |k 0/120000/ |k 1/120000/120300/ |p 1 |x j | ||
| 999 | |a KXP-PPN1581153945 |e 3025919043 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Gesehen am 20.09.2018"],"origin":[{"dateIssuedDisp":"12 May 2017","dateIssuedKey":"2017"}],"title":[{"subtitle":"a GISAXS study","title_sort":"Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface","title":"Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface"}],"language":["eng"],"person":[{"display":"Veschgini, Mariam","family":"Veschgini","given":"Mariam","role":"aut"},{"role":"aut","given":"Wasim","family":"Abuillan","display":"Abuillan, Wasim"},{"family":"Inoue","display":"Inoue, Shigeto","role":"aut","given":"Shigeto"},{"display":"Mielke, Salomé","family":"Mielke","given":"Salomé","role":"aut"},{"given":"Motomu","role":"aut","display":"Tanaka, Motomu","family":"Tanaka"}],"id":{"doi":["10.1002/cphc.201700325"],"eki":["1581153945"]},"relHost":[{"disp":"Size, shape, and lateral correlation of highly uniform, mesoscopic, self-assembled domains of fluorocarbon-hydrocarbon diblocks at the air/water interface a GISAXS studyChemPhysChem","language":["eng"],"part":{"year":"2017","text":"18(2017), 19, Seite 2791-2798","pages":"2791-2798","extent":"8","volume":"18","issue":"19"},"note":["Fortsetzung der Druck-Ausgabe","Gesehen am 10.11.2022"],"type":{"media":"Online-Ressource","bibl":"periodical"},"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"[2000]-","publisher":"Wiley-VCH Verl."}],"titleAlt":[{"title":"a European journal of physical chemistry and chemical physics"}],"title":[{"title":"ChemPhysChem","title_sort":"ChemPhysChem"}],"recId":"320642216","pubHistory":["1.2000 -"],"physDesc":[{"extent":"Online-Ressource"}],"id":{"eki":["320642216"],"issn":["1439-7641"],"zdb":["2025223-7"],"doi":["10.1002/(ISSN)1439-7641"]}}],"physDesc":[{"extent":"8 S."}],"name":{"displayForm":["Mariam Veschgini, Wasim Abuillan, Shigeto Inoue, Akihisa Yamamoto, Salomé Mielke, Xianhe Liu, Oleg Konovalov, Marie Pierre Krafft, and Motomu Tanaka"]},"recId":"1581153945"} | ||
| SRT | |a VESCHGINIMSIZESHAPEA1220 | ||