Triptycene-bis(aroyleneimidazole)s as non-fullerene acceptors: the missing links
The syntheses of four triptycene-bis(aroyleneimidazole)s—the missing links with respect to the previously reported triptycene-mono(aroyleneimidazole)s and triptycene-tris(aroyleneimidazole)s—are presented. Their optoelectronic properties and use as non-fullerene acceptors in organic photovoltaics wi...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
23 November 2017
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| In: |
ChemPlusChem
Year: 2017, Volume: 82, Issue: 12, Pages: 1390-1395 |
| ISSN: | 2192-6506 |
| DOI: | 10.1002/cplu.201700428 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/cplu.201700428 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/cplu.201700428 
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| Author Notes: | Elisabeth H. Menke, David Leibold, Felix J. Berger, Frank Rominger, Yana Vaynzof and Michael Mastalerz |
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| 520 | |a The syntheses of four triptycene-bis(aroyleneimidazole)s—the missing links with respect to the previously reported triptycene-mono(aroyleneimidazole)s and triptycene-tris(aroyleneimidazole)s—are presented. Their optoelectronic properties and use as non-fullerene acceptors in organic photovoltaics with poly(4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl[3-fluoro-2-(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl) (PTB7) as a donor are described; these systems reach a maximum power conversion efficiency of 2 %. Furthermore, the effect of molecular symmetry on the photovoltaic device performance is discussed. | ||
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