Cover Image

Optical properties and sequence information of tin-centered conjugated microporous polymers

We synthesized conjugated microporous polymers (CMPs) based on tetrakis(4-ethynylphenyl)stannane and diiodobenzene as tectons, using Sonogashira couplings under different conditions. Through variation of the reaction conditions (catalysts, bases and solvents), appearance, surface area and emission p...

Full description

Saved in:
Bibliographic Details
Main Authors: Uptmoor, Andrea Christina (Author) , Elbert, Sven (Author) , Wacker, Irene (Author) , Schröder, Rasmus R. (Author) , Mastalerz, Michael (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 2018
In: Chemistry - a European journal
Year: 2018, Volume: 24, Issue: 7, Pages: 1674-1680
ISSN:1521-3765
DOI:10.1002/chem.201704572
Online Access:Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/chem.201704572
Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201704572
Get full text
Author Notes:Andrea C. Uptmoor, Ruben Ilyas, Sven M. Elbert, Irene Wacker, Rasmus R. Schröder, Michael Mastalerz, Jan Freudenberg, and Uwe H.F. Bunz
Description
Summary:We synthesized conjugated microporous polymers (CMPs) based on tetrakis(4-ethynylphenyl)stannane and diiodobenzene as tectons, using Sonogashira couplings under different conditions. Through variation of the reaction conditions (catalysts, bases and solvents), appearance, surface area and emission properties of the formed CMPs were significantly altered. Wet-chemical, acid-mediated digestion and analysis of the resulting struts of these otherwise insoluble networks give insight into the molecular setup.
Item Description:Gesehen am 10.10.2018
Article was first published on 30 November 2017
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201704572

Similar Items