Gold(III)-catalyzed site-selective and divergent synthesis of 2-Aminopyrroles and Quinoline-based Polyazaheterocycles
A facile, site-selective, and divergent approach to construct 2-aminopyrroles and quinoline-fused polyazaheterocycles enabled by a simple gold(III) catalyst from ynamides and anthranils under mild reaction conditions is described. This one-pot strategy uses readily available starting materials, proc...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 11, 2018
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| In: |
Angewandte Chemie
Year: 2018, Jahrgang: 130, Heft: 50, Pages: 16787-16791 |
| ISSN: | 1521-3757 |
| DOI: | 10.1002/ange.201810369 |
| Online-Zugang: | Resolving-System, Volltext: http://dx.doi.org/10.1002/ange.201810369 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.201810369 
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| Verfasserangaben: | Zhongyi Zeng, Hongming Jin, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| 520 | |a A facile, site-selective, and divergent approach to construct 2-aminopyrroles and quinoline-fused polyazaheterocycles enabled by a simple gold(III) catalyst from ynamides and anthranils under mild reaction conditions is described. This one-pot strategy uses readily available starting materials, proceeds in a highly step- and atom-economical manner, with broad substrate scope and scale-up potential. The key element for success in this tandem reaction is a catalyst-directed preferred quenching of the in situ generated gold carbene intermediates by a nucleophilic benzyl/2-furylmethyl moiety on the ynamides as an alternative to the known C−H annulation leading to indoles. | ||
| 650 | 4 | |a Aminopyrrole | |
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| 650 | 4 | |a Chinolin-fusionierte Polyazaheterocyclen | |
| 650 | 4 | |a Regioselektive und divergente Synthese | |
| 650 | 4 | |a α-Iminogoldcarbene | |
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