An unconventional helical push-pull system for solar cells
The synthesis, photophysical and electrochemical characterization, theoretical calculations and photovoltaic studies of a push-pull dye with an unconventional nonplanar tetrathiahelicene π−spacer between the donor-acceptor groups, are reported. The molecule exhibits suitable HOMO LUMO levels to be u...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2019
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| In: |
Dyes and pigments
Year: 2018, Jahrgang: 161, Pages: 382-388 |
| ISSN: | 0143-7208 |
| DOI: | 10.1016/j.dyepig.2018.09.050 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1016/j.dyepig.2018.09.050 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0143720818311720 
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| Verfasserangaben: | Davide Dova, Silvia Cauteruccio, Norberto Manfredi, Stefan Prager, Andreas Dreuw, Serena Arnaboldi, Patrizia R. Mussini, Emanuela Licandro, Alessandro Abbotto |
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| 520 | |a The synthesis, photophysical and electrochemical characterization, theoretical calculations and photovoltaic studies of a push-pull dye with an unconventional nonplanar tetrathiahelicene π−spacer between the donor-acceptor groups, are reported. The molecule exhibits suitable HOMO LUMO levels to be used in DSSC. The presence of the donor-acceptor helical architecture allows the internal charge transfer and subsequent electron injection to the conduction band of TiO2 leading to the good photocurrent value of 4.6 mAcm−2. | ||
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