Rare earth metal oxazoline complexes in asymmetric catalysis
Polydentate oxazolines have been employed as highly effective stereodirecting ligands for asymmetric catalysis with metals from across most of the periodic table. Despite their highly versatile coordination chemistry, the use of these ligands tends to be polarised towards late transition metals; the...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 Sep 2012
|
| In: |
Chemical communications
Year: 2012, Volume: 48, Issue: 86, Pages: 10587-10599 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C2CC34997C |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1039/C2CC34997C Verlag, Volltext: https://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc34997c |
| Author Notes: | Benjamin D. Ward, Lutz H. Gade |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1588202216 | ||
| 003 | DE-627 | ||
| 005 | 20220815114351.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 190228s2012 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/C2CC34997C |2 doi | |
| 035 | |a (DE-627)1588202216 | ||
| 035 | |a (DE-576)518202216 | ||
| 035 | |a (DE-599)BSZ518202216 | ||
| 035 | |a (OCoLC)1341040706 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Ward, Benjamin D. |e VerfasserIn |0 (DE-588)1172311447 |0 (DE-627)104111270X |0 (DE-576)51450319X |4 aut | |
| 245 | 1 | 0 | |a Rare earth metal oxazoline complexes in asymmetric catalysis |c Benjamin D. Ward, Lutz H. Gade |
| 264 | 1 | |c 17 Sep 2012 | |
| 300 | |a 13 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 28.02.2019 | ||
| 520 | |a Polydentate oxazolines have been employed as highly effective stereodirecting ligands for asymmetric catalysis with metals from across most of the periodic table. Despite their highly versatile coordination chemistry, the use of these ligands tends to be polarised towards late transition metals; their use with early transition metals and the f-elements is significantly less developed. This current article aims to review the coordination chemistry and catalytic applications of Group 3 and lanthanide complexes supported by ligands possessing oxazoline moieties. Oxazoline-containing ligands were first employed in molecular lanthanide catalysis as early as 1997, yet there is still a significant void in the chemical literature in this respect. The ligands generally employed include bis(oxazolinyl)methane (“BOX”), 2,6-bis(oxazolinyl)pyridine (“pybox”), 1,1,1-tris(oxazolinyl)ethane (“trisox”), and others. The complexes are employed in a wide-range of catalytic applications, especially in Lewis acid catalysis, but also in the stereospecific polymerisation of olefins. | ||
| 700 | 1 | |a Gade, Lutz H. |d 1963- |e VerfasserIn |0 (DE-588)1019812737 |0 (DE-627)691026750 |0 (DE-576)358881870 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical communications |d Cambridge : Soc., 1965 |g 48(2012), 86, Seite 10587-10599 |h Online-Ressource |w (DE-627)268759081 |w (DE-600)1472881-3 |w (DE-576)077609867 |x 1364-548X |7 nnas |a Rare earth metal oxazoline complexes in asymmetric catalysis |
| 773 | 1 | 8 | |g volume:48 |g year:2012 |g number:86 |g pages:10587-10599 |g extent:13 |a Rare earth metal oxazoline complexes in asymmetric catalysis |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1039/C2CC34997C |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc34997c |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20190228 | ||
| 993 | |a Article | ||
| 994 | |a 2012 | ||
| 998 | |g 1019812737 |a Gade, Lutz H. |m 1019812737:Gade, Lutz H. |d 120000 |d 120200 |e 120000PG1019812737 |e 120200PG1019812737 |k 0/120000/ |k 1/120000/120200/ |p 2 |y j | ||
| 999 | |a KXP-PPN1588202216 |e 3056974917 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"recId":"268759081","note":["Gesehen am 20.02.24"],"origin":[{"dateIssuedKey":"1965","dateIssuedDisp":"1965-","publisher":"Soc. ; Soc.","publisherPlace":"Cambridge ; London"}],"pubHistory":["1965 - 1968; 1996 -"],"id":{"zdb":["1472881-3"],"eki":["268759081"],"issn":["1364-548X"]},"language":["eng"],"name":{"displayForm":["The Royal Society of Chemistry"]},"titleAlt":[{"title":"ChemComm online"},{"title":"Chemical communications online"}],"corporate":[{"display":"Royal Society of Chemistry","role":"isb"}],"title":[{"subtitle":"ChemComm","title_sort":"Chemical communications","title":"Chemical communications"}],"part":{"text":"48(2012), 86, Seite 10587-10599","year":"2012","pages":"10587-10599","issue":"86","volume":"48","extent":"13"},"disp":"Rare earth metal oxazoline complexes in asymmetric catalysisChemical communications","physDesc":[{"extent":"Online-Ressource"}],"type":{"bibl":"periodical","media":"Online-Ressource"}}],"recId":"1588202216","note":["Gesehen am 28.02.2019"],"origin":[{"dateIssuedDisp":" 17 Sep 2012","dateIssuedKey":"2012"}],"id":{"doi":["10.1039/C2CC34997C"],"eki":["1588202216"]},"physDesc":[{"extent":"13 S."}],"title":[{"title_sort":"Rare earth metal oxazoline complexes in asymmetric catalysis","title":"Rare earth metal oxazoline complexes in asymmetric catalysis"}],"person":[{"given":"Benjamin D.","display":"Ward, Benjamin D.","role":"aut","family":"Ward"},{"role":"aut","display":"Gade, Lutz H.","given":"Lutz H.","family":"Gade"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"name":{"displayForm":["Benjamin D. Ward, Lutz H. Gade"]},"language":["eng"]} | ||
| SRT | |a WARDBENJAMRAREEARTHM1720 | ||