A cationic gold complex cleaves BArF24
A sterically shielded cationic NHC gold complex IPr**Au-BArF24 without solvent coordination has been prepared in situ in CH2Cl2. The monovalent transition metal electrophile, a “soft proton”, heterolytically activates the C-B bond of the weakly coordinating counterion tetrakis[3,5-bis(trifluoromethy...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
03 Oct 2012
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| In: |
Chemical communications
Year: 2012, Volume: 48, Issue: 92, Pages: 11325-11327 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C2CC36171J |
| Online Access: | Verlag, Volltext: https://doi.org/10.1039/C2CC36171J Verlag, Volltext: https://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc36171j 
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| Author Notes: | Simone G. Weber, David Zahner, Frank Rominger, Bernd F. Straub |
| Summary: | A sterically shielded cationic NHC gold complex IPr**Au-BArF24 without solvent coordination has been prepared in situ in CH2Cl2. The monovalent transition metal electrophile, a “soft proton”, heterolytically activates the C-B bond of the weakly coordinating counterion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate at room temperature. |
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| Item Description: | Gesehen am 03.04.2019 |
| Physical Description: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C2CC36171J |