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A cationic gold complex cleaves BArF24

A sterically shielded cationic NHC gold complex IPr**Au-BArF24 without solvent coordination has been prepared in situ in CH2Cl2. The monovalent transition metal electrophile, a “soft proton”, heterolytically activates the C-B bond of the weakly coordinating counterion tetrakis[3,5-bis(trifluoromethy...

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Hauptverfasser: Weber, Simone G. (VerfasserIn) , Zahner, David (VerfasserIn) , Rominger, Frank (VerfasserIn) , Straub, Bernd Franz (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 03 Oct 2012
In: Chemical communications
Year: 2012, Jahrgang: 48, Heft: 92, Pages: 11325-11327
ISSN:1364-548X
DOI:10.1039/C2CC36171J
Online-Zugang:Verlag, Volltext: https://doi.org/10.1039/C2CC36171J
Verlag, Volltext: https://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc36171j
Volltext
Verfasserangaben:Simone G. Weber, David Zahner, Frank Rominger, Bernd F. Straub

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