Cover Image

High-pressure optical floating-zone growth of Li2FeSiO4 single crystals

We report the growth of mm-sized Pmnb-Li2FeSiO4 single crystals by means of the optical floating-zone method at high argon pressure and describe the conditions required for a stable growth process. The crystal structure is determined and refined by single-crystal X-ray diffraction. The lattice const...

Full description

Saved in:
Bibliographic Details
Main Authors: Hergett, Waldemar (Author) , Neef, Christoph (Author) , Wadepohl, Hubert (Author) , Meyer, Hans-Peter (Author) , Thauer, Elisa (Author) , Klingeler, Rüdiger (Author)
Format: Article (Journal)
Language:English
Published: [1 June 2019]
In: Journal of crystal growth
Year: 2019, Volume: 515, Pages: 37-43
DOI:10.1016/j.jcrysgro.2019.03.010
Online Access:Verlag, Volltext: https://doi.org/10.1016/j.jcrysgro.2019.03.010
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022024819301642
Get full text
Author Notes:Waldemar Hergett, Christoph Neef, Hubert Wadepohl, Hans-Peter Meyer, Mahmoud M. Abdel-Hafiez, Clemens Ritter, Elisa Thauer, Rüdiger Klingeler

MARC

LEADER 00000caa a2200000 c 4500
001 1663320462
003 DE-627
005 20220816135127.0
007 cr uuu---uuuuu
008 190416s2019 xx |||||o 00| ||eng c
024 7 |a 10.1016/j.jcrysgro.2019.03.010  |2 doi 
035 |a (DE-627)1663320462 
035 |a (DE-599)KXP1663320462 
035 |a (OCoLC)1341209702 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 29  |2 sdnb 
100 1 |a Hergett, Waldemar  |e VerfasserIn  |0 (DE-588)1155252748  |0 (DE-627)1016572034  |0 (DE-576)501496548  |4 aut 
245 1 0 |a High-pressure optical floating-zone growth of Li2FeSiO4 single crystals  |c Waldemar Hergett, Christoph Neef, Hubert Wadepohl, Hans-Peter Meyer, Mahmoud M. Abdel-Hafiez, Clemens Ritter, Elisa Thauer, Rüdiger Klingeler 
246 3 3 |a High-pressure optical floating-zone growth of Li 2 FeSiO 4 single crystals 
264 1 |c [1 June 2019] 
300 |b Illustrationen 
300 |a 7 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Die Zahlen "2" und "4" sind im Titel tiefgestellt 
500 |a Available online: 12 March 2019 
500 |a Gesehen am 16.04.2019 
520 |a We report the growth of mm-sized Pmnb-Li2FeSiO4 single crystals by means of the optical floating-zone method at high argon pressure and describe the conditions required for a stable growth process. The crystal structure is determined and refined by single-crystal X-ray diffraction. The lattice constants amount to a=6.27837(3) Å, b=10.62901(6) Å and c=5.03099(3) Å at 100K. In addition, we present high-resolution neutron powder diffraction data that suggest that the slight Li - Fe site exchange seems to be intrinsic to this material. High quality of the crystal is confirmed by very sharp anomalies in the static magnetic susceptibility and in the specific heat associated with the onset of long-range antiferromagnetic order at TN=17.0(5) K and pronounced magnetic anisotropy for the three crystallographic axes. Furthermore, magnetic susceptibility excludes the presence of sizable amounts of magnetic impurity phases. 
650 4 |a A1. Characterization 
650 4 |a A1. Crystal structure 
650 4 |a A2. Floating zone technique 
650 4 |a A2. Single crystal growth 
650 4 |a B2. Lithium-ion battery materials 
650 4 |a B2. Magnetic materials 
700 1 |a Neef, Christoph  |e VerfasserIn  |0 (DE-588)1026888697  |0 (DE-627)727545841  |0 (DE-576)372235530  |4 aut 
700 1 |a Wadepohl, Hubert  |e VerfasserIn  |0 (DE-588)1019812354  |0 (DE-627)691026572  |0 (DE-576)358886724  |4 aut 
700 1 |a Meyer, Hans-Peter  |d 1957-  |e VerfasserIn  |0 (DE-588)1019805293  |0 (DE-627)691023123  |0 (DE-576)358795338  |4 aut 
700 1 |a Thauer, Elisa  |d 1990-  |e VerfasserIn  |0 (DE-588)1155251563  |0 (DE-627)1016569971  |0 (DE-576)501493786  |4 aut 
700 1 |a Klingeler, Rüdiger  |d 1969-  |e VerfasserIn  |0 (DE-588)128948736  |0 (DE-627)38613720X  |0 (DE-576)187850720  |4 aut 
773 0 8 |i Enthalten in  |t Journal of crystal growth  |d Amsterdam [u.a.] : Elsevier, 1967  |g 515(2019), Seite 37-43  |h Online-Ressource  |w (DE-627)266014488  |w (DE-600)1466514-1  |w (DE-576)074959689  |7 nnas  |a High-pressure optical floating-zone growth of Li2FeSiO4 single crystals 
773 1 8 |g volume:515  |g year:2019  |g pages:37-43  |g extent:7  |a High-pressure optical floating-zone growth of Li2FeSiO4 single crystals 
856 4 0 |u https://doi.org/10.1016/j.jcrysgro.2019.03.010  |x Verlag  |x Resolving-System  |3 Volltext 
856 4 0 |u http://www.sciencedirect.com/science/article/pii/S0022024819301642  |x Verlag  |3 Volltext 
951 |a AR 
992 |a 20190416 
993 |a Article 
994 |a 2019 
998 |g 128948736  |a Klingeler, Rüdiger  |m 128948736:Klingeler, Rüdiger  |d 130000  |d 130700  |e 130000PK128948736  |e 130700PK128948736  |k 0/130000/  |k 1/130000/130700/  |p 8  |y j 
998 |g 1155251563  |a Thauer, Elisa  |m 1155251563:Thauer, Elisa  |d 130000  |d 130700  |e 130000PT1155251563  |e 130700PT1155251563  |k 0/130000/  |k 1/130000/130700/  |p 7 
998 |g 1019805293  |a Meyer, Hans-Peter  |m 1019805293:Meyer, Hans-Peter  |d 120000  |d 121000  |e 120000PM1019805293  |e 121000PM1019805293  |k 0/120000/  |k 1/120000/121000/  |p 4 
998 |g 1019812354  |a Wadepohl, Hubert  |m 1019812354:Wadepohl, Hubert  |d 120000  |d 120200  |e 120000PW1019812354  |e 120200PW1019812354  |k 0/120000/  |k 1/120000/120200/  |p 3 
998 |g 1026888697  |a Neef, Christoph  |m 1026888697:Neef, Christoph  |p 2 
998 |g 1155252748  |a Hergett, Waldemar  |m 1155252748:Hergett, Waldemar  |d 130000  |d 130700  |e 130000PH1155252748  |e 130700PH1155252748  |k 0/130000/  |k 1/130000/130700/  |p 1  |x j 
999 |a KXP-PPN1663320462  |e 3422625275 
BIB |a Y 
SER |a journal 
JSO |a {"title":[{"title":"High-pressure optical floating-zone growth of Li2FeSiO4 single crystals","title_sort":"High-pressure optical floating-zone growth of Li2FeSiO4 single crystals"}],"relHost":[{"title":[{"title_sort":"Journal of crystal growth","title":"Journal of crystal growth"}],"disp":"High-pressure optical floating-zone growth of Li2FeSiO4 single crystalsJournal of crystal growth","language":["eng"],"origin":[{"dateIssuedKey":"1967","publisherPlace":"Amsterdam [u.a.] ; Amsterdam","publisher":"Elsevier ; North-Holland Publ. Co.","dateIssuedDisp":"1967-"}],"physDesc":[{"extent":"Online-Ressource"}],"part":{"text":"515(2019), Seite 37-43","extent":"7","year":"2019","pages":"37-43","volume":"515"},"recId":"266014488","note":["Gesehen am 07.02.13"],"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["1.1967 - 312.2010; Vol. 313.2010 -"],"id":{"zdb":["1466514-1"],"eki":["266014488"]}}],"name":{"displayForm":["Waldemar Hergett, Christoph Neef, Hubert Wadepohl, Hans-Peter Meyer, Mahmoud M. Abdel-Hafiez, Clemens Ritter, Elisa Thauer, Rüdiger Klingeler"]},"id":{"eki":["1663320462"],"doi":["10.1016/j.jcrysgro.2019.03.010"]},"titleAlt":[{"title":"High-pressure optical floating-zone growth of Li 2 FeSiO 4 single crystals"}],"physDesc":[{"noteIll":"Illustrationen","extent":"7 S."}],"origin":[{"dateIssuedDisp":"[1 June 2019]","dateIssuedKey":"2019"}],"language":["eng"],"person":[{"display":"Hergett, Waldemar","roleDisplay":"VerfasserIn","role":"aut","given":"Waldemar","family":"Hergett"},{"roleDisplay":"VerfasserIn","role":"aut","given":"Christoph","display":"Neef, Christoph","family":"Neef"},{"family":"Wadepohl","display":"Wadepohl, Hubert","role":"aut","roleDisplay":"VerfasserIn","given":"Hubert"},{"family":"Meyer","display":"Meyer, Hans-Peter","roleDisplay":"VerfasserIn","role":"aut","given":"Hans-Peter"},{"display":"Thauer, Elisa","given":"Elisa","roleDisplay":"VerfasserIn","role":"aut","family":"Thauer"},{"family":"Klingeler","display":"Klingeler, Rüdiger","role":"aut","roleDisplay":"VerfasserIn","given":"Rüdiger"}],"recId":"1663320462","note":["Die Zahlen \"2\" und \"4\" sind im Titel tiefgestellt","Available online: 12 March 2019","Gesehen am 16.04.2019"],"type":{"bibl":"article-journal","media":"Online-Ressource"}} 
SRT |a HERGETTWALHIGHPRESSU1201 

Similar Items