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Silver-catalyzed carboxylative cyclization of primary propargyl alcohols with CO2

By using silver complexes with bulky ligands such as DavePhos or N-heterocyclic carbenes, propargylic alcohols are smoothly converted with CO2 into a unique class of unexplored cyclic alkylidene carbonates. These systems, for the first time, also achieve the direct carboxylative cyclization of prima...

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Hauptverfasser: Dabral, Saumya (VerfasserIn) , Schießl, Jasmin (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: February 20, 2019
In: Organic letters
Year: 2019, Jahrgang: 21, Heft: 5, Pages: 1422-1425
ISSN:1523-7052
DOI:10.1021/acs.orglett.9b00156
Online-Zugang:Verlag, Volltext: https://doi.org/10.1021/acs.orglett.9b00156
Volltext
Verfasserangaben:Saumya Dabral, Bilguun Bayarmagnai, Marko Hermsen, Jasmin Schießl, Verena Mormul, A. Stephen K. Hashmi, and Thomas Schaub

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