Stabilization by Benzannulation: Butterfly Azaacenes
Soluble butterfly-shaped tetraazapentacenes and tetraazaheptacenes were prepared by condensation or Stille coupling with a stannafluorene. The stability of the benzo-winged tetraazaheptacene is dramatically increased through the fourfold benzannulation, yet its acene character is retained to a signi...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
02 July 2018
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| In: |
Chemistry - a European journal
Year: 2018, Jahrgang: 24, Heft: 49, Pages: 12801-12805 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201803118 |
| Online-Zugang: | Verlag, Pay-per-use, Volltext: https://doi.org/10.1002/chem.201803118 Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803118 |
| Verfasserangaben: | Matthias Müller, Hilmar Reiss, Olena Tverskoy, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz |
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| 520 | |a Soluble butterfly-shaped tetraazapentacenes and tetraazaheptacenes were prepared by condensation or Stille coupling with a stannafluorene. The stability of the benzo-winged tetraazaheptacene is dramatically increased through the fourfold benzannulation, yet its acene character is retained to a significant extent. | ||
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