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Silicon tris(perchloro)dioxolene: a neutral triplet diradical

The reaction of ortho-quinones with silicon tetraiodide leads to neutral silicon trisdioxolenes in high yield, delivering the unknown oxidized form of triscatecholatosilicate dianions and the first example of open-shell semiquinonates connected via a single non-metal center. Silicon tris(perchloro)d...

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Hauptverfasser: Maskey, Rezisha (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Greb, Lutz (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2019
In: Angewandte Chemie. International edition
Year: 2018, Jahrgang: 58, Heft: 11, Pages: 3616-3619
ISSN:1521-3773
DOI:10.1002/anie.201812989
Online-Zugang:Verlag, Volltext: https://doi.org/10.1002/anie.201812989
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201812989
Volltext
Verfasserangaben:Rezisha Maskey, Hubert Wadepohl, and Lutz Greb

MARC

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