Dual gold/silver catalysis involving alkynylgold(III) intermediates formed by oxidative addition and silver-catalyzed C−H activation for the direct alkynylation of cyclopropenes
While gold-mediated synergistic catalytic processes involving transmetalations with other metals are well understood, AuI/AuIII cycles in these reactions are rarely reported. Herein a gold-catalyzed direct alkynylation of cyclopropenes is enabled by two operating catalytic cycles, an oxidative catal...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 12, 2019
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| In: |
Angewandte Chemie. International edition
Year: 2019, Volume: 58, Issue: 15, Pages: 5129-5133 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201812577 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1002/anie.201812577 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201812577 
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| Author Notes: | Yangyang Yang, Patrick Antoni, Marc Zimmer, Kohei Sekine, Florian F. Mulks, Long Hu, Lumin Zhang, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| 520 | |a While gold-mediated synergistic catalytic processes involving transmetalations with other metals are well understood, AuI/AuIII cycles in these reactions are rarely reported. Herein a gold-catalyzed direct alkynylation of cyclopropenes is enabled by two operating catalytic cycles, an oxidative catalytic cycle involving an alkynyl AuIII complex formed by oxidative addition and one involving a silver-mediated C−H activation. | ||
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