Denitrogenative Pd/Cu-catalyzed Suzuki-type cross-coupling of Aryltrifluoroborates with Arylhydrazine hydrochlorides in water under room temperature

A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a ran...

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Hauptverfasser: Wang, Guofang (VerfasserIn) , Cheng, Kai (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2018
In: Applied organometallic chemistry
Year: 2017, Jahrgang: 32, Heft: 3
ISSN:1099-0739
DOI:10.1002/aoc.4203
Online-Zugang:Verlag, Volltext: https://doi.org/10.1002/aoc.4203
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/aoc.4203
Volltext
Verfasserangaben:Guofang Wang, Mengting Meng, Liping Deng, Kai Cheng, Chenze Qi
Beschreibung
Zusammenfassung:A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.
Beschreibung:First published: 21 December 2017
Gesehen am 17.06.2019
Beschreibung:Online Resource
ISSN:1099-0739
DOI:10.1002/aoc.4203