Denitrogenative Pd/Cu-catalyzed Suzuki-type cross-coupling of Aryltrifluoroborates with Arylhydrazine hydrochlorides in water under room temperature
A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a ran...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2018
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| In: |
Applied organometallic chemistry
Year: 2017, Jahrgang: 32, Heft: 3 |
| ISSN: | 1099-0739 |
| DOI: | 10.1002/aoc.4203 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1002/aoc.4203 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/aoc.4203 |
| Verfasserangaben: | Guofang Wang, Mengting Meng, Liping Deng, Kai Cheng, Chenze Qi |
| Zusammenfassung: | A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen. |
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| Beschreibung: | First published: 21 December 2017 Gesehen am 17.06.2019 |
| Beschreibung: | Online Resource |
| ISSN: | 1099-0739 |
| DOI: | 10.1002/aoc.4203 |