Guanidine electron donors and silver halides: interplay and competition between redox, coordination and polymerization reactions
Redox reactions compete with coordination and polymerization reactions when the organic electron donor and ligand, 1,2,4,5-tetrakis(tetramethylguanidino)benzene (1), is dissolved together with silver halides AgX (X = Cl, Br or I) in solvents of different polarity. The complex results obtained for th...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2012
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| In: |
European journal of inorganic chemistry
Year: 2011, Issue: 4, Pages: 695-704 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201101002 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1002/ejic.201101002 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201101002 |
| Author Notes: | Dimitri Emeljanenko, Julian Horn, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel |
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| 520 | |a Redox reactions compete with coordination and polymerization reactions when the organic electron donor and ligand, 1,2,4,5-tetrakis(tetramethylguanidino)benzene (1), is dissolved together with silver halides AgX (X = Cl, Br or I) in solvents of different polarity. The complex results obtained for the relatively simple system 1/AgX highlight the importance of solvent effects. A variety of chain polymers have been synthesized in which the guanidine electron-donor building blocks are connected by silver halide clusters of different sizes. | ||
| 534 | |c 2011 | ||
| 650 | 4 | |a Coordination compounds | |
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| 650 | 4 | |a Halides | |
| 650 | 4 | |a Redox chemistry | |
| 650 | 4 | |a Silver | |
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