Calix[4]pyrrole hydridosilicate: the elusive planar tetracoordinate silicon imparts striking stability to Its anionic silicon hydride
Anionic hydridosilicates are highly reactive and strong hydride donors. In contrast, calix[4]pyrrole hydridosilicate is an entirely water-stable, anionic silicon hydride, which does not show hydridic reactivity. However, it still acts as an electron donor and enables the detection of a single electr...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
November 30, 2018
|
| In: |
Journal of the American Chemical Society
Year: 2018, Volume: 140, Issue: 50, Pages: 17409-17412 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.8b11137 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1021/jacs.8b11137
|
| Author Notes: | Fabian Ebner, Lutz Greb |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1669058719 | ||
| 003 | DE-627 | ||
| 005 | 20230428192207.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 190712s2018 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/jacs.8b11137 |2 doi | |
| 035 | |a (DE-627)1669058719 | ||
| 035 | |a (DE-599)KXP1669058719 | ||
| 035 | |a (OCoLC)1341233587 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Ebner, Fabian |d 1992- |e VerfasserIn |0 (DE-588)112315452X |0 (DE-627)876435053 |0 (DE-576)481628479 |4 aut | |
| 245 | 1 | 0 | |a Calix[4]pyrrole hydridosilicate |b the elusive planar tetracoordinate silicon imparts striking stability to Its anionic silicon hydride |c Fabian Ebner, Lutz Greb |
| 264 | 1 | |c November 30, 2018 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 12.07.2019 | ||
| 520 | |a Anionic hydridosilicates are highly reactive and strong hydride donors. In contrast, calix[4]pyrrole hydridosilicate is an entirely water-stable, anionic silicon hydride, which does not show hydridic reactivity. However, it still acts as an electron donor and enables the detection of a single electron transfer process in the reduction chemistry with hydridosilicates. Most important, these unusual properties are imparted by the unique planar structure of its elusive parent neutral silane-substantiating the effect of planar tetracoordinate silicon for the first time. | ||
| 700 | 1 | |a Greb, Lutz |e VerfasserIn |0 (DE-588)1043619879 |0 (DE-627)770726526 |0 (DE-576)395158265 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a American Chemical Society |t Journal of the American Chemical Society |d Washington, DC : ACS Publications, 1879 |g 140(2018), 50, Seite 17409-17412 |w (DE-627)268132836 |w (DE-600)1472210-0 |w (DE-576)090854284 |x 1520-5126 |7 nnas |
| 773 | 1 | 8 | |g volume:140 |g year:2018 |g number:50 |g pages:17409-17412 |g extent:4 |a Calix[4]pyrrole hydridosilicate the elusive planar tetracoordinate silicon imparts striking stability to Its anionic silicon hydride |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jacs.8b11137 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jacs.8b11137 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20190712 | ||
| 993 | |a Article | ||
| 994 | |a 2018 | ||
| 998 | |g 1043619879 |a Greb, Lutz |m 1043619879:Greb, Lutz |d 120000 |d 120200 |e 120000PG1043619879 |e 120200PG1043619879 |k 0/120000/ |k 1/120000/120200/ |p 2 |y j | ||
| 998 | |g 112315452X |a Ebner, Fabian |m 112315452X:Ebner, Fabian |d 120000 |d 120200 |e 120000PE112315452X |e 120200PE112315452X |k 0/120000/ |k 1/120000/120200/ |p 1 |x j | ||
| 999 | |a KXP-PPN1669058719 |e 349287455X | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"origin":[{"dateIssuedDisp":"November 30, 2018","dateIssuedKey":"2018"}],"id":{"eki":["1669058719"],"doi":["10.1021/jacs.8b11137"]},"person":[{"family":"Ebner","role":"aut","display":"Ebner, Fabian","given":"Fabian"},{"given":"Lutz","role":"aut","display":"Greb, Lutz","family":"Greb"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"title":[{"title":"Calix[4]pyrrole hydridosilicate","title_sort":"Calix[4]pyrrole hydridosilicate","subtitle":"the elusive planar tetracoordinate silicon imparts striking stability to Its anionic silicon hydride"}],"name":{"displayForm":["Fabian Ebner, Lutz Greb"]},"recId":"1669058719","physDesc":[{"extent":"4 S."}],"relHost":[{"origin":[{"dateIssuedKey":"1879","publisherPlace":"Washington, DC ; Washington, DC","publisher":"ACS Publications ; American Chemical Society","dateIssuedDisp":"1879-"}],"part":{"text":"140(2018), 50, Seite 17409-17412","year":"2018","pages":"17409-17412","issue":"50","volume":"140","extent":"4"},"id":{"zdb":["1472210-0"],"eki":["268132836"],"issn":["1520-5126"]},"name":{"displayForm":["Ed.: Allen J. Bard [u.a.]"]},"disp":"American Chemical SocietyJournal of the American Chemical Society","title":[{"title_sort":"Journal of the American Chemical Society","title":"Journal of the American Chemical Society","subtitle":"JACS"}],"language":["eng"],"pubHistory":["1.1879 -"],"titleAlt":[{"title":"JACS"},{"title":"web edition"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"recId":"268132836","note":["Gesehen am 25.08.2020"],"corporate":[{"role":"aut","display":"American Chemical Society"}]}],"note":["Gesehen am 12.07.2019"],"language":["eng"]} | ||
| SRT | |a EBNERFABIACALIX4PYRR3020 | ||