True blue through oxidation: a thiaazulenic heterophenoquinone as electrochrome

A thiaazulenic quinone TAQ was synthesized and its optical and redox properties were investigated. The deep blue-colored compound is readily and reversibly reduced to the colorless anionic state. Electrochromic films were prepared and showed reversible switching behavior for the anodically coloring...

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Bibliographic Details
Main Authors: Intorp, Sebastian (Author) , Kushida, Soh (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Hinkel, Felix Peter (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 06 February 2019
In: Chemistry - a European journal
Year: 2019, Volume: 25, Issue: 21, Pages: 5412-5415
ISSN:1521-3765
DOI:10.1002/chem.201900535
Online Access:Verlag, Volltext: https://doi.org/10.1002/chem.201900535
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201900535
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Author Notes:Sebastian N. Intorp, Soh Kushida, Evgenia Dmitrieva, Alexey A. Popov, Frank Rominger, Jan Freudenberg, Felix Hinkel, Uwe H.F. Bunz
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Summary:A thiaazulenic quinone TAQ was synthesized and its optical and redox properties were investigated. The deep blue-colored compound is readily and reversibly reduced to the colorless anionic state. Electrochromic films were prepared and showed reversible switching behavior for the anodically coloring and NIR electrochromic material.
Item Description:Gesehen am 23.07.2019
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201900535