Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines
The octadentate bispidine ligand L (bispidine=3,7-diazabicyclo[3,3,1]nonane) with two pyridine groups at C2 and C4 and two picolinates at N3 and N7, providing two tertiary amines, four pyridines and two carboxylates to metal ions, has been coordinated to lanthanide(III) ions (SmIII, EuIII, TbIII, Dy...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2019
|
| In: |
Inorganica chimica acta
Year: 2019, Jahrgang: 484, Pages: 464-468 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2018.09.078 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1016/j.ica.2018.09.078 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0020169318312593 
|
| Verfasserangaben: | Felix Braun, Peter Comba, Laura Grimm, Dirk-Peter Herten, Bianca Pokrandt, Hubert Wadepohl |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1670450848 | ||
| 003 | DE-627 | ||
| 005 | 20230426082348.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 190801s2019 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.ica.2018.09.078 |2 doi | |
| 035 | |a (DE-627)1670450848 | ||
| 035 | |a (DE-599)KXP1670450848 | ||
| 035 | |a (OCoLC)1341235243 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Braun, Felix |d 1990- |e VerfasserIn |0 (DE-588)121289197X |0 (DE-627)1702964191 |4 aut | |
| 245 | 1 | 0 | |a Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines |c Felix Braun, Peter Comba, Laura Grimm, Dirk-Peter Herten, Bianca Pokrandt, Hubert Wadepohl |
| 264 | 1 | |c 2019 | |
| 300 | |a 5 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Available online 29 September 2018 | ||
| 500 | |a Gesehen am 01.08.2019 | ||
| 520 | |a The octadentate bispidine ligand L (bispidine=3,7-diazabicyclo[3,3,1]nonane) with two pyridine groups at C2 and C4 and two picolinates at N3 and N7, providing two tertiary amines, four pyridines and two carboxylates to metal ions, has been coordinated to lanthanide(III) ions (SmIII, EuIII, TbIII, DyIII, HoIII). The single crystal X-ray structures of [TbIII(L)(NO3)] and [HoIII(L)(OH2)](TFA) (TFA=trifluoracetate) have been determined and define the complexes as 9-coordinate with a monodentate nitrate or a water molecule completing the coordination sphere. Spectroscopy indicates that in solution all complexes are 9-coordinate with an OH2 coordinated to the lanthanide(III) center. Absorption and emission spectra show that the ligands function as antennas with UV excitation (260nm) leading to relatively high intensity emission in the visible region (500-600nm) with millisecond lifetimes of the excited states. | ||
| 650 | 4 | |a Antenna effect | |
| 650 | 4 | |a Bispidine | |
| 650 | 4 | |a Lanthanide | |
| 650 | 4 | |a Luminescence | |
| 700 | 1 | |a Comba, Peter |d 1953- |e VerfasserIn |0 (DE-588)122976843 |0 (DE-627)082271712 |0 (DE-576)160608988 |4 aut | |
| 700 | 1 | |a Herten, Dirk-Peter |e VerfasserIn |0 (DE-588)1020454768 |0 (DE-627)691223882 |0 (DE-576)360394051 |4 aut | |
| 700 | 1 | |a Pokrandt, Bianca |e VerfasserIn |0 (DE-588)1152971999 |0 (DE-627)1014333350 |0 (DE-576)499978382 |4 aut | |
| 700 | 1 | |a Wadepohl, Hubert |e VerfasserIn |0 (DE-588)1019812354 |0 (DE-627)691026572 |0 (DE-576)358886724 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Inorganica chimica acta |d New York, NY [u.a.] : Elsevier, 1967 |g 484(2019), Seite 464-468 |h Online-Ressource |w (DE-627)301510946 |w (DE-600)1484441-2 |w (DE-576)081952694 |x 0020-1693 |7 nnas |a Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines |
| 773 | 1 | 8 | |g volume:484 |g year:2019 |g pages:464-468 |g extent:5 |a Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.ica.2018.09.078 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u http://www.sciencedirect.com/science/article/pii/S0020169318312593 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20190801 | ||
| 993 | |a Article | ||
| 994 | |a 2019 | ||
| 998 | |g 1019812354 |a Wadepohl, Hubert |m 1019812354:Wadepohl, Hubert |d 120000 |d 120200 |e 120000PW1019812354 |e 120200PW1019812354 |k 0/120000/ |k 1/120000/120200/ |p 6 |y j | ||
| 998 | |g 1152971999 |a Pokrandt, Bianca |m 1152971999:Pokrandt, Bianca |d 120000 |d 120200 |e 120000PP1152971999 |e 120200PP1152971999 |k 0/120000/ |k 1/120000/120200/ |p 5 | ||
| 998 | |g 1020454768 |a Herten, Dirk-Peter |m 1020454768:Herten, Dirk-Peter |d 700000 |d 718000 |e 700000PH1020454768 |e 718000PH1020454768 |k 0/700000/ |k 1/700000/718000/ |p 4 | ||
| 998 | |g 122976843 |a Comba, Peter |m 122976843:Comba, Peter |d 120000 |d 120200 |e 120000PC122976843 |e 120200PC122976843 |k 0/120000/ |k 1/120000/120200/ |p 2 | ||
| 998 | |g 121289197X |a Braun, Felix |m 121289197X:Braun, Felix |d 120000 |d 120300 |e 120000PB121289197X |e 120300PB121289197X |k 0/120000/ |k 1/120000/120300/ |p 1 |x j | ||
| 999 | |a KXP-PPN1670450848 |e 3502496269 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title":"Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines","title_sort":"Ligand-sensitized lanthanide(III) luminescence with octadentate bispidines"}],"origin":[{"dateIssuedKey":"2019","dateIssuedDisp":"2019"}],"name":{"displayForm":["Felix Braun, Peter Comba, Laura Grimm, Dirk-Peter Herten, Bianca Pokrandt, Hubert Wadepohl"]},"id":{"doi":["10.1016/j.ica.2018.09.078"],"eki":["1670450848"]},"physDesc":[{"extent":"5 S."}],"relHost":[{"note":["Gesehen am 23.04.13"],"part":{"year":"2019","extent":"5","pages":"464-468","text":"484(2019), Seite 464-468","volume":"484"},"recId":"301510946","type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["1.1967 - 363.2010; Vol. 364.2010 -"],"id":{"eki":["301510946"],"zdb":["1484441-2"],"issn":["0020-1693"]},"title":[{"title_sort":"Inorganica chimica acta","title":"Inorganica chimica acta","subtitle":"the international inorganic chemistry journal"}],"language":["eng"],"disp":"Ligand-sensitized lanthanide(III) luminescence with octadentate bispidinesInorganica chimica acta","physDesc":[{"extent":"Online-Ressource"}],"origin":[{"publisher":"Elsevier","dateIssuedDisp":"1967-","publisherPlace":"New York, NY [u.a.]","dateIssuedKey":"1967"}]}],"person":[{"given":"Felix","roleDisplay":"VerfasserIn","role":"aut","display":"Braun, Felix","family":"Braun"},{"display":"Comba, Peter","given":"Peter","role":"aut","roleDisplay":"VerfasserIn","family":"Comba"},{"role":"aut","roleDisplay":"VerfasserIn","given":"Dirk-Peter","display":"Herten, Dirk-Peter","family":"Herten"},{"family":"Pokrandt","given":"Bianca","roleDisplay":"VerfasserIn","role":"aut","display":"Pokrandt, Bianca"},{"family":"Wadepohl","display":"Wadepohl, Hubert","given":"Hubert","role":"aut","roleDisplay":"VerfasserIn"}],"language":["eng"],"note":["Available online 29 September 2018","Gesehen am 01.08.2019"],"recId":"1670450848","type":{"bibl":"article-journal","media":"Online-Ressource"}} | ||
| SRT | |a BRAUNFELIXLIGANDSENS2019 | ||