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On the basic extraction properties of a phenyl trifluoromethyl sulfone-based GANEX system containing CyMe4-BTBP and TBP

A Grouped ActiNide EXtraction (GANEX) process for the extraction of actinides from used nuclear fuel for transmutation purposes has been investigated. The studied solvent consists of phenyl trifluoromethyl sulfone (FS-13), CyMe4-BTBP, and TBP, a combination that has previously shown promising result...

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Bibliographic Details
Main Authors: Halleröd, Jenny (Author) , Wagner, Christoph (Author) , Panak, Petra (Author)
Format: Article (Journal)
Language:English
Published: 18 Jul 2018
In: Solvent extraction and ion exchange
Year: 2018, Volume: 36, Issue: 4, Pages: 360-372
ISSN:1532-2262
DOI:10.1080/07366299.2018.1497043
Online Access:Verlag, Volltext: https://doi.org/10.1080/07366299.2018.1497043
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Author Notes:Jenny Halleröd, Christian Ekberg, Thea Authen, Laura Bertolo, Mu Lin, Bohumír Grüner, Jaroslav Švehla, Christoph Wagner, Andreas Geist, Petra Panak, and Emma Aneheim
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Summary:A Grouped ActiNide EXtraction (GANEX) process for the extraction of actinides from used nuclear fuel for transmutation purposes has been investigated. The studied solvent consists of phenyl trifluoromethyl sulfone (FS-13), CyMe4-BTBP, and TBP, a combination that has previously shown promising results. The time to reach extraction equilibrium for the system has been found to be less than 20 min. A 2:1 complex has been found between CyMe4-BTBP and americium(III) or curium(III), whereas plutonium(IV) and CyMe4-BTBP create a 1:1 complex. The extraction of fission product is low in the system.
Item Description:Im Titel die 4 ist tiefgestellt
Gesehen am 21.08.2019
Physical Description:Online Resource
ISSN:1532-2262
DOI:10.1080/07366299.2018.1497043

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