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Bis(perchlorocatecholato)silane - a neutral silicon Lewis super acid

No neutral silicon Lewis super acids are known to date. We report on the synthesis of bis(perchlorocatecholato)silane and verify its Lewis super acidity by computation (DLPNO-CCSD(T)) and experiment (fluoride abstraction from SbF6−). The exceptional affinity towards donors is further demonstrated by...

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Hauptverfasser: Maskey, Rezisha (VerfasserIn) , Schädler, Marcel (VerfasserIn) , Legler, Claudia (VerfasserIn) , Greb, Lutz (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: [February 5, 2018]
In: Angewandte Chemie. International edition
Year: 2017, Jahrgang: 57, Heft: 6, Pages: 1717-1720
ISSN:1521-3773
DOI:10.1002/anie.201712155
Online-Zugang:Verlag, Volltext: https://doi.org/10.1002/anie.201712155
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201712155
Volltext
Verfasserangaben:Rezisha Maskey, Marcel Schädler, Claudia Legler, and Lutz Greb

MARC

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