Design and synthesis of novel functionalized fused oxazepine and diazepine analogues containing coumarin backbone through domino reaction
A simple and straightforward approach has been developed for the synthesis of functionalized fused oxazepine and diazepine analogues containing coumarin backbone. The approach was done through three-component reaction of 4-chloro-3-formylcoumarin, triphenyl-λ5-phosphanylidene derivatives and 2-amino...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
31 May 2019
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| In: |
ChemistrySelect
Year: 2019, Jahrgang: 4, Heft: 20, Pages: 6403-6407 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201900918 |
| Online-Zugang: | Resolving-System, Volltext: http://dx.doi.org/10.1002/slct.201900918 Resolving-System, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201900918 
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| Verfasserangaben: | Samane Poursan, Somayeh Ahadi, Saeed Balalaie, Frank Rominger, and Hamid Reza Bijanzadeh |
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| 520 | |a A simple and straightforward approach has been developed for the synthesis of functionalized fused oxazepine and diazepine analogues containing coumarin backbone. The approach was done through three-component reaction of 4-chloro-3-formylcoumarin, triphenyl-λ5-phosphanylidene derivatives and 2-aminophenol or o-phenylenediamine derivatives in the presence of cesium carbonate at room temperature. Carrying out the same reaction without base led to 4-aminoarylcoumarins. Mild reaction conditions and synthesis of fused functionalized heterocyclic backbones are advantages of this approach. | ||
| 650 | 4 | |a 4-Chloro-3-formyl coumarin | |
| 650 | 4 | |a Benzodiazepine | |
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