Mixed iodonium-, phosphonium-, arsonium-, sulfoniumdiazonium ylides in reactions with nucleophiles

The reactions of mixed ylides containing a diazonium fragment and an "onium" group of different nature with nucleophiles were studied. In the iodonium-diazonium and sulfoniumdiazonium ylide, the nucleophile first of all substitutes the iodonium and sulfonium group. A series of hetaryl-subs...

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Hauptverfasser: Podrugina, Tatyana A. (VerfasserIn) , Pavlova, A. S. (VerfasserIn) , Vinogradov, D. S. (VerfasserIn) , Shuvalov, M. V. (VerfasserIn) , Potapov, I. D. (VerfasserIn) , Levina, I. I. (VerfasserIn) , Mironov, A. V. (VerfasserIn) , Gleiter, Rolf (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 15 April 2019
In: Russian chemical bulletin
Year: 2019, Jahrgang: 68, Heft: 2, Pages: 284-292
ISSN:1573-9171
DOI:10.1007/s11172-019-2384-8
Online-Zugang:Verlag, Volltext: https://doi.org/10.1007/s11172-019-2384-8
Volltext
Verfasserangaben:T.A. Podrugina, A.S. Pavlova, D.S. Vinogradov, M.V. Shuvalov, I.D. Potapov, I.I. Levina, A.V. Mironov, and R. Gleiter
Beschreibung
Zusammenfassung:The reactions of mixed ylides containing a diazonium fragment and an "onium" group of different nature with nucleophiles were studied. In the iodonium-diazonium and sulfoniumdiazonium ylide, the nucleophile first of all substitutes the iodonium and sulfonium group. A series of hetaryl-substituted phosphazines was obtained by a one-pot process of nucleophilic substitution in a diazonium-iodonium ylide with subsequent nucleophilic addition of triarylphosphine at the diazo group.
Beschreibung:Gesehen am 12.11.2019
Beschreibung:Online Resource
ISSN:1573-9171
DOI:10.1007/s11172-019-2384-8