Light-induced mechanistic divergence in gold(I) catalysis: revisiting the reactivity of diazonium salts

In a systematic study of the Au-catalyzed reaction of o-alkynylphenols with aryldiazonium salts, we find that essentially the same reaction conditions lead to a change in mechanism when a light source is applied. If the reaction is carried out at room temperature using a AuI catalyst, the diazonium...

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Main Authors:	Taschinski, Svenja (Author) , Döpp, René (Author) , Ackermann, Martin (Author) , Rominger, Frank (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author)
Format:	Article (Journal)
Language:	English
Published:	October 11, 2019
In:	Angewandte Chemie. International edition Year: 2019, Volume: 58, Issue: 47, Pages: 16988-16993
ISSN:	1521-3773
DOI:	10.1002/anie.201908268
Online Access:	Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/anie.201908268 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201908268
Author Notes:	Svenja Taschinski, René Döpp, Martin Ackermann, Frank Rominger, Folkert de Vries, Maximilian F.S.J. Menger, Matthias Rudolph, A. Stephen K. Hashmi, and Johannes E.M.N. Klein

Light-induced mechanistic divergence in gold(I) catalysis: revisiting the reactivity of diazonium salts by Taschinski, Svenja (Author) , Döpp, René (Author) , Ackermann, Martin (Author) , Rominger, Frank (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author) ,

in: Angewandte Chemie, 131 (2019), 47, Seite 17144-17149

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Light-induced mechanistic divergence in gold(I) catalysis: revisiting the reactivity of diazonium salts

Light-induced mechanistic divergence in gold(I) catalysis: revisiting the reactivity of diazonium salts by Taschinski, Svenja (Author) , Döpp, René (Author) , Ackermann, Martin (Author) , Rominger, Frank (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author) ,

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