Calix[4]pyrrole aluminate: a planar tetracoordinate aluminum(III) anion and its unusual lewis acidity
Tetracoordinate aluminum(III) anions are generally tetrahedral and non-Lewis acidic. Herein, we describe the first planar tetracoordinate aluminum anion. The anion is isolated in its free form, representing a new “anti-van’t Hoff/Le Bel” case. Despite its negative charge, it remains Lewis acidic and...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
October 30, 2019
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| In: |
Journal of the American Chemical Society
Year: 2019, Volume: 141, Issue: 45, Pages: 18009-18012 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.9b10628 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1021/jacs.9b10628
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| Author Notes: | Fabian Ebner, Hubert Wadepohl, and Lutz Greb |
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| 520 | |a Tetracoordinate aluminum(III) anions are generally tetrahedral and non-Lewis acidic. Herein, we describe the first planar tetracoordinate aluminum anion. The anion is isolated in its free form, representing a new “anti-van’t Hoff/Le Bel” case. Despite its negative charge, it remains Lewis acidic and permits the formation of various unique adducts, e.g., a dianionic p-block metal hydride. Turning an inert spectator anion into a Lewis acid by planarization verifies theoretical predictions made 40 years ago, ultimately connects “anti-van’t Hoff/Le Bel” structure with reactivity, and pushes | ||
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