Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms
Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp2-sp2-hybridized diborane(4) compounds are used for this purpose; these can be regarded as boryl-substituted boranes and consequently react as electrophiles. In contrast, the chemistry o...
Saved in:
| Main Author: | |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
07 Febrary 2018
|
| In: |
European journal of inorganic chemistry
Year: 2018, Issue: 20/21, Pages: 2139-2154 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201800031 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1002/ejic.201800031 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800031 
|
| Author Notes: | Hans-Jörg Himmel |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1687416672 | ||
| 003 | DE-627 | ||
| 005 | 20241209094145.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200115s2018 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/ejic.201800031 |2 doi | |
| 035 | |a (DE-627)1687416672 | ||
| 035 | |a (DE-599)KXP1687416672 | ||
| 035 | |a (OCoLC)1341298088 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Himmel, Hans-Jörg |d 1970- |e VerfasserIn |0 (DE-588)120090368 |0 (DE-627)080439683 |0 (DE-576)292036159 |4 aut | |
| 245 | 1 | 0 | |a Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms |c Hans-Jörg Himmel |
| 246 | 3 | 3 | |a Nucleophilic neutral Diborane (4) compounds with sp3-sp3-hybridized Boron atoms |
| 264 | 1 | |c 07 Febrary 2018 | |
| 300 | |a 16 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a First published: 07 Febrary 2018 | ||
| 500 | |a Gesehen am 15.01.2020 | ||
| 500 | |a sp3: Zahl 3 ist hochgestellt | ||
| 520 | |a Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp2-sp2-hybridized diborane(4) compounds are used for this purpose; these can be regarded as boryl-substituted boranes and consequently react as electrophiles. In contrast, the chemistry of nucleophilic, electron-rich sp3-sp3-hybridized diborane(4) compounds is a very underdeveloped research field. This review highlights some aspects of this chemistry, showing that it offers great new opportunities for diboration and boron-boron coupling reactions. The discussion focusses primarily on especially nucleophilic doubly guanidinate-bridged diborane(4) compounds. | ||
| 650 | 4 | |a Boranes | |
| 650 | 4 | |a Boron-boron coupling | |
| 650 | 4 | |a Diborane(4) | |
| 650 | 4 | |a Diboration | |
| 650 | 4 | |a Hydrides | |
| 650 | 4 | |a Nucleophilicity | |
| 773 | 0 | 8 | |i Enthalten in |t European journal of inorganic chemistry |d Weinheim : Wiley-VCH, 1998 |g (2018), 20/21, Seite 2139-2154 |h Online-Ressource |w (DE-627)269534520 |w (DE-600)1475009-0 |w (DE-576)077884671 |x 1099-0682 |7 nnas |a Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms |
| 773 | 1 | 8 | |g year:2018 |g number:20/21 |g pages:2139-2154 |g extent:16 |a Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms |
| 856 | 4 | 0 | |u https://doi.org/10.1002/ejic.201800031 |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800031 |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200115 | ||
| 993 | |a Article | ||
| 994 | |a 2018 | ||
| 998 | |g 120090368 |a Himmel, Hans-Jörg |m 120090368:Himmel, Hans-Jörg |d 120000 |d 120200 |e 120000PH120090368 |e 120200PH120090368 |k 0/120000/ |k 1/120000/120200/ |p 1 |x j |y j | ||
| 999 | |a KXP-PPN1687416672 |e 3575511985 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"language":["eng"],"titleAlt":[{"title":"Nucleophilic neutral Diborane (4) compounds with sp3-sp3-hybridized Boron atoms"}],"person":[{"given":"Hans-Jörg","role":"aut","family":"Himmel","display":"Himmel, Hans-Jörg"}],"relHost":[{"part":{"text":"(2018), 20/21, Seite 2139-2154","extent":"16","issue":"20/21","pages":"2139-2154","year":"2018"},"language":["eng"],"id":{"zdb":["1475009-0"],"issn":["1099-0682"],"doi":["10.1002/(ISSN)1099-0682c"],"eki":["269534520"]},"physDesc":[{"extent":"Online-Ressource"}],"recId":"269534520","type":{"media":"Online-Ressource","bibl":"periodical"},"disp":"Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atomsEuropean journal of inorganic chemistry","title":[{"title_sort":"European journal of inorganic chemistry","title":"European journal of inorganic chemistry"}],"note":["Gesehen am 27.02.24","Fortsetzung der Druck-Ausgabe"],"origin":[{"dateIssuedDisp":"1998-","publisher":"Wiley-VCH","dateIssuedKey":"1998","publisherPlace":"Weinheim"}],"pubHistory":["Volume 1998, Issue 1 (January 1998)-"]}],"recId":"1687416672","name":{"displayForm":["Hans-Jörg Himmel"]},"physDesc":[{"extent":"16 S."}],"id":{"doi":["10.1002/ejic.201800031"],"eki":["1687416672"]},"note":["First published: 07 Febrary 2018","Gesehen am 15.01.2020","sp3: Zahl 3 ist hochgestellt"],"origin":[{"dateIssuedDisp":"07 Febrary 2018","dateIssuedKey":"2018"}],"title":[{"title_sort":"Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms","title":"Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms"}],"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a HIMMELHANSNUCLEOPHIL0720 | ||