Acyl migration versus epoxidation in gold catalysis: facile, switchable, and atom-economic synthesis of acylindoles and quinoline derivatives
We report a switchable synthesis of acylindoles and quinoline derivatives via gold-catalyzed annulations of anthranils and ynamides. α-Imino gold carbenes, generated in situ from anthranils and an N,O-coordinated gold(III) catalyst, undergo electrophilic attack to the aryl π-bond, followed by unexpe...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2020
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| In: |
Angewandte Chemie. International edition
Year: 2020, Jahrgang: 59, Heft: 1, Pages: 471-478 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201912334 |
| Online-Zugang: | Resolving-System, Volltext: https://doi.org/10.1002/anie.201912334 Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201912334 
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| Verfasserangaben: | Xianhai Tian, Lina Song, Kaveh Farshadfar, Matthias Rudolph, Frank Rominger, Thomas Oeser, Alireza Ariafard, and A. Stephen K. Hashmi |
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