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Acyl migration versus epoxidation in gold catalysis: facile, switchable, and atom-economic synthesis of acylindoles and quinoline derivatives

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We report a switchable synthesis of acylindoles and quinoline derivatives via gold-catalyzed annulations of anthranils and ynamides. α-Imino gold carbenes, generated in situ from anthranils and an N,O-coordinated gold(III) catalyst, undergo electrophilic attack to the aryl π-bond, followed by unexpe...

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Main Authors: Tian, Xianhai (Author) , Song, Lina (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Oeser, Thomas (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 2020
In: Angewandte Chemie. International edition
Year: 2020, Volume: 59, Issue: 1, Pages: 471-478
ISSN:1521-3773
DOI:10.1002/anie.201912334
Online Access:Resolving-System, Volltext: https://doi.org/10.1002/anie.201912334
Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201912334
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Author Notes:Xianhai Tian, Lina Song, Kaveh Farshadfar, Matthias Rudolph, Frank Rominger, Thomas Oeser, Alireza Ariafard, and A. Stephen K. Hashmi
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Acyl migration versus epoxidation in gold catalysis: facile, switchable, and atom-economic synthesis of acylindoles and quinoline derivatives by Tian, Xianhai (Author) , Song, Lina (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Oeser, Thomas (Author) , Hashmi, A. Stephen K. (Author) ,


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