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Azaacenodibenzosuberones

A series of dibenzosuberone-fused N-heteroacenes was obtained by the condensation of dibenzosuberonetriketone with a series of substituted diamino- and tetramino-arenes. The electron-deficient triketone reacts at room temperature and furnishes the pyrazine or bis-pyrazine-containing condensation pro...

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Bibliographic Details
Main Authors: Brosius, Victor (Author) , Müller, Matthias (Author) , Borstelmann, Jan (Author) , Rominger, Frank (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 2020
In: The journal of organic chemistry
Year: 2020, Volume: 85, Issue: 1, Pages: 296-300
ISSN:1520-6904
DOI:10.1021/acs.joc.9b02756
Online Access:Verlag, Volltext: https://doi.org/10.1021/acs.joc.9b02756
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Author Notes:Victor Brosius, Matthias Müller, Jan Borstelmann, Frank Rominger, Jan Freudenberg, Uwe H.F. Bunz
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Summary:A series of dibenzosuberone-fused N-heteroacenes was obtained by the condensation of dibenzosuberonetriketone with a series of substituted diamino- and tetramino-arenes. The electron-deficient triketone reacts at room temperature and furnishes the pyrazine or bis-pyrazine-containing condensation products in good to excellent yield. The targets all display negative curvature according to single crystal structures.
Item Description:Published: November 5, 2019
Gesehen am 27.01.2020
Physical Description:Online Resource
ISSN:1520-6904
DOI:10.1021/acs.joc.9b02756

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