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Shape-persistent (4+4) imine cages with a truncated tetrahedral geometry

The synthesis of shape-persistent organic cage compounds is often based on the usage of multiple dynamic covalent bond formation (such as imines) of readily available precursors. By careful choice of the precursors geometry, the geometry and size of the resulting cage can be accurately designed and...

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Bibliographische Detailangaben
Hauptverfasser: Lauer, Jochen (VerfasserIn) , Rominger, Frank (VerfasserIn) , Mastalerz, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2018
In: Chemistry - a European journal
Year: 2017, Jahrgang: 24, Heft: 8, Pages: 1816-1820
ISSN:1521-3765
DOI:10.1002/chem.201705713
Online-Zugang:Verlag, Volltext: https://doi.org/10.1002/chem.201705713
Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201705713
Volltext
Verfasserangaben:Jochen C. Lauer, Wen-Shan Zhang, Frank Rominger, Rasmus R. Schröder, and Michael Mastalerz

MARC

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520 |a The synthesis of shape-persistent organic cage compounds is often based on the usage of multiple dynamic covalent bond formation (such as imines) of readily available precursors. By careful choice of the precursors geometry, the geometry and size of the resulting cage can be accurately designed and indeed a number of different geometries and sizes have been realized to date. Despite of this fact, little is known about the precursors conformational rigidity and steric preorganization of reacting functional groups on the outcome of the reaction. Herein, the influence of conformational rigidity in the precursors on the formation of a [4+4] imine cage with truncated tetrahedral geometry is discussed. 
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