A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate: the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n
The complexation of Eu(III) by lactate and the ligand protonation were studied at 25 °C as a function of the ionic strength (Im = 0.10 - 5.61 mol kg−1 H2O, NaCl). The experimental formation constants of the three [Eu(Lac)n]3-n (n = 1, 2, 3) mononuclear complexes (log β’n) and the protonation constan...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
24 June 2019
|
| In: |
Thermochimica acta
Year: 2019, Jahrgang: 679 |
| ISSN: | 1872-762X |
| DOI: | 10.1016/j.tca.2019.178316 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.tca.2019.178316 Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0040603119301030 
|
| Verfasserangaben: | Andrej Skerencak-Frech, Franziska Taube, Pier Luigi Zanonato, Margret Acker, Petra J. Panak, Plinio Di Bernardo |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1692381008 | ||
| 003 | DE-627 | ||
| 005 | 20220818012850.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200312s2019 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.tca.2019.178316 |2 doi | |
| 035 | |a (DE-627)1692381008 | ||
| 035 | |a (DE-599)KXP1692381008 | ||
| 035 | |a (OCoLC)1341309963 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Skerencak-Frech, Andrej |e VerfasserIn |0 (DE-588)141626550 |0 (DE-627)630395519 |0 (DE-576)325028133 |4 aut | |
| 245 | 1 | 2 | |a A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate |b the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n |c Andrej Skerencak-Frech, Franziska Taube, Pier Luigi Zanonato, Margret Acker, Petra J. Panak, Plinio Di Bernardo |
| 264 | 1 | |c 24 June 2019 | |
| 300 | |a 7 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 12.03.2020 | ||
| 500 | |a Im Titel sind die Buchstaben "m", "n"und "r" tiefgestellt | ||
| 520 | |a The complexation of Eu(III) by lactate and the ligand protonation were studied at 25 °C as a function of the ionic strength (Im = 0.10 - 5.61 mol kg−1 H2O, NaCl). The experimental formation constants of the three [Eu(Lac)n]3-n (n = 1, 2, 3) mononuclear complexes (log β’n) and the protonation constant of lactate (log β’HLac) were determined by potentiometric titrations. The experimental values were extrapolated to zero ionic strength by means of the SIT approach, yielding the thermodynamic constants (log β0n) and the specific ion interaction coefficients of the ionic species (ε(i,k)). The reaction enthalpies (ΔrH’m,n), determined independently by isothermal calorimetry, and entropies (ΔrS’m,n) are also reported. The ionic strength dependence of ΔrH’m,n was fitted by means of the enthalpy SIT approach, giving the standard reaction enthalpies (ΔrH0m,n), entropies (ΔrS0m,n) and the partial molar enthalpy specific ion interaction coefficients (ΔεL(i,k)). The results show negative conditional reaction enthalpies for all complexes, which become more exothermic with increasing ionic strength. Simultaneously, the ΔrS’m,n decrease steadily with Im, resulting in a gradual change of the driving force of the reactions: at low ionic strength the reaction is driven almost exclusively by entropy. As Im increases the contribution of the enthalpy term becomes relevant and the reactions are driven almost equally by ΔrH’m,n and ΔrS’m,n at the highest value of Im studied. | ||
| 650 | 4 | |a Europium(III) | |
| 650 | 4 | |a Ionic strength | |
| 650 | 4 | |a Lactate | |
| 650 | 4 | |a Microcalorimetry | |
| 650 | 4 | |a Thermodynamics | |
| 700 | 1 | |a Taube, Franziska |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zanonato, Pier Luigi |e VerfasserIn |4 aut | |
| 700 | 1 | |a Acker, Margret |e VerfasserIn |4 aut | |
| 700 | 1 | |a Panak, Petra |e VerfasserIn |0 (DE-588)1084656000 |0 (DE-627)848640217 |0 (DE-576)456626727 |4 aut | |
| 700 | 1 | |a Di Bernardo, Plinio |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Thermochimica acta |d Amsterdam [u.a.] : Elsevier Science, 1970 |g 679(2019) Artikel-Nummer 178316, 7 Seiten |h Online-Ressource |w (DE-627)306712628 |w (DE-600)1500974-9 |w (DE-576)251938166 |x 1872-762X |7 nnas |a A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n |
| 773 | 1 | 8 | |g volume:679 |g year:2019 |g extent:7 |a A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.tca.2019.178316 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u http://www.sciencedirect.com/science/article/pii/S0040603119301030 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200312 | ||
| 993 | |a Article | ||
| 994 | |a 2019 | ||
| 998 | |g 1084656000 |a Panak, Petra |m 1084656000:Panak, Petra |d 120000 |d 120300 |e 120000PP1084656000 |e 120300PP1084656000 |k 0/120000/ |k 1/120000/120300/ |p 5 | ||
| 998 | |g 141626550 |a Skerencak-Frech, Andrej |m 141626550:Skerencak-Frech, Andrej |p 1 |x j | ||
| 999 | |a KXP-PPN1692381008 |e 3607119937 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"subtitle":"the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n","title":"A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate","title_sort":"potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate"}],"recId":"1692381008","relHost":[{"physDesc":[{"extent":"Online-Ressource"}],"language":["eng"],"origin":[{"publisherPlace":"Amsterdam [u.a.]","publisher":"Elsevier Science","dateIssuedKey":"1970","dateIssuedDisp":"1970-"}],"recId":"306712628","pubHistory":["1.1970 - 526.2011; Vol. 527.2012 -"],"title":[{"title":"Thermochimica acta","title_sort":"Thermochimica acta","subtitle":"an international journal concerned with all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering"}],"disp":"A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate the ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,nThermochimica acta","part":{"extent":"7","text":"679(2019) Artikel-Nummer 178316, 7 Seiten","volume":"679","year":"2019"},"type":{"media":"Online-Ressource","bibl":"periodical"},"id":{"eki":["306712628"],"issn":["1872-762X"],"zdb":["1500974-9"]},"note":["Gesehen am 15.11.23"]}],"origin":[{"dateIssuedDisp":"24 June 2019","dateIssuedKey":"2019"}],"language":["eng"],"physDesc":[{"extent":"7 S."}],"person":[{"display":"Skerencak-Frech, Andrej","role":"aut","family":"Skerencak-Frech","given":"Andrej","roleDisplay":"VerfasserIn"},{"roleDisplay":"VerfasserIn","given":"Franziska","family":"Taube","role":"aut","display":"Taube, Franziska"},{"display":"Zanonato, Pier Luigi","role":"aut","family":"Zanonato","given":"Pier Luigi","roleDisplay":"VerfasserIn"},{"roleDisplay":"VerfasserIn","given":"Margret","family":"Acker","role":"aut","display":"Acker, Margret"},{"roleDisplay":"VerfasserIn","given":"Petra","family":"Panak","role":"aut","display":"Panak, Petra"},{"role":"aut","display":"Di Bernardo, Plinio","roleDisplay":"VerfasserIn","family":"Di Bernardo","given":"Plinio"}],"note":["Gesehen am 12.03.2020","Im Titel sind die Buchstaben \"m\", \"n\"und \"r\" tiefgestellt"],"name":{"displayForm":["Andrej Skerencak-Frech, Franziska Taube, Pier Luigi Zanonato, Margret Acker, Petra J. Panak, Plinio Di Bernardo"]},"id":{"eki":["1692381008"],"doi":["10.1016/j.tca.2019.178316"]},"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a SKERENCAKFPOTENTIOME2420 | ||