Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction
Identifying cheap, yet effective, oxygen evolution catalysts is critical to the advancement of water splitting. Using liquid exfoliated Co(OH)2 nanosheets as a model system, a simple procedure is developed to maximize the activity of any oxygen evolution reaction nanocatalyst. First the nanosheet ed...
Saved in:
| Main Authors: | , , , , , , , , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
30 January 2018
|
| In: |
Advanced energy materials
Year: 2018, Volume: 8, Issue: 15 |
| ISSN: | 1614-6840 |
| DOI: | 10.1002/aenm.201702965 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/aenm.201702965 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201702965 
|
| Author Notes: | David McAteer, Ian J. Godwin, Zheng Ling, Andrew Harvey, Lily He, Conor S. Boland, Victor Vega‐Mayoral, Beata Szydłowska, Aurélie A. Rovetta, Claudia Backes, John B. Boland, Xin Chen, Michael E. G. Lyons, and Jonathan N. Coleman |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1693190214 | ||
| 003 | DE-627 | ||
| 005 | 20230427033619.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200324s2018 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/aenm.201702965 |2 doi | |
| 035 | |a (DE-627)1693190214 | ||
| 035 | |a (DE-599)KXP1693190214 | ||
| 035 | |a (OCoLC)1341311072 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a McAteer, David |e VerfasserIn |0 (DE-588)1206953861 |0 (DE-627)1693190818 |4 aut | |
| 245 | 1 | 0 | |a Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction |c David McAteer, Ian J. Godwin, Zheng Ling, Andrew Harvey, Lily He, Conor S. Boland, Victor Vega‐Mayoral, Beata Szydłowska, Aurélie A. Rovetta, Claudia Backes, John B. Boland, Xin Chen, Michael E. G. Lyons, and Jonathan N. Coleman |
| 264 | 1 | |c 30 January 2018 | |
| 300 | |a 11 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist die Zahl "2" tiefer gestellt | ||
| 500 | |a Gesehen am 24.03.2020 | ||
| 520 | |a Identifying cheap, yet effective, oxygen evolution catalysts is critical to the advancement of water splitting. Using liquid exfoliated Co(OH)2 nanosheets as a model system, a simple procedure is developed to maximize the activity of any oxygen evolution reaction nanocatalyst. First the nanosheet edges are confirmed as the active areas by analyzing the catalytic activity as a function of nanosheet size. This allows the authors to select the smallest nanosheets (length ≈50 nm) as the best performing catalysts. While the number of active sites per unit electrode area can be increased via the electrode thickness, this is found to be impossible beyond ≈10 µm due to mechanical instabilities. However, adding carbon nanotubes increases both toughness and conductivity significantly. These enhancements mean that composite electrodes consisting of small Co(OH)2 nanosheets and 10 wt% nanotubes can be made into freestanding films with thickness of up to 120 µm with no apparent electrical limitations. The presence of diffusion limitations results in an optimum electrode thickness of 70 µm, yielding a current density of 50 mA cm−2 at an overpotential of 235 mV, close to the state of the art in the field. Applying this procedure to a high-performance catalyst such as NiFeOx should significantly surpass the state of the art. | ||
| 650 | 4 | |a exfoliation | |
| 650 | 4 | |a layered materials | |
| 650 | 4 | |a nanocatalysts | |
| 650 | 4 | |a oxygen evolution reaction | |
| 650 | 4 | |a size-dependence | |
| 700 | 1 | |a Godwin, Ian J. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Ling, Zheng |e VerfasserIn |4 aut | |
| 700 | 1 | |a Harvey, Andrew |e VerfasserIn |4 aut | |
| 700 | 1 | |a He, Lily |e VerfasserIn |4 aut | |
| 700 | 1 | |a Boland, Conor S. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Vega‐Mayoral, Victor |e VerfasserIn |4 aut | |
| 700 | 1 | |a Szydłowska, Beata |e VerfasserIn |4 aut | |
| 700 | 1 | |a Rovetta, Aurélie A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Backes, Claudia |d 1982- |e VerfasserIn |0 (DE-588)1019617233 |0 (DE-627)685502767 |0 (DE-576)358450535 |4 aut | |
| 700 | 1 | |a Boland, John B. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Chen, Xin |e VerfasserIn |4 aut | |
| 700 | 1 | |a Lyons, Michael E. G. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Coleman, Jonathan N. |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Advanced energy materials |d Weinheim : Wiley-VCH, 2011 |g 8(2018,15) Artikel-Nummer 1702965, 11 Seiten |h Online-Ressource |w (DE-627)647301024 |w (DE-600)2594556-7 |w (DE-576)338208070 |x 1614-6840 |7 nnas |a Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction |
| 773 | 1 | 8 | |g volume:8 |g year:2018 |g number:15 |g extent:11 |a Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction |
| 856 | 4 | 0 | |u https://doi.org/10.1002/aenm.201702965 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201702965 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200324 | ||
| 993 | |a Article | ||
| 994 | |a 2018 | ||
| 998 | |g 1019617233 |a Backes, Claudia |m 1019617233:Backes, Claudia |d 120000 |d 120300 |e 120000PB1019617233 |e 120300PB1019617233 |k 0/120000/ |k 1/120000/120300/ |p 10 | ||
| 999 | |a KXP-PPN1693190214 |e 3612425900 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"id":{"eki":["647301024"],"doi":["10.1002/(ISSN)1614-6840"],"zdb":["2594556-7"],"issn":["1614-6840"]},"origin":[{"publisherPlace":"Weinheim","publisher":"Wiley-VCH","dateIssuedDisp":"[2011]-"}],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Advanced energy materials","title_sort":"Advanced energy materials"}],"part":{"volume":"8","text":"8(2018,15) Artikel-Nummer 1702965, 11 Seiten","extent":"11","year":"2018","issue":"15"},"pubHistory":["1.2011 -"],"language":["eng"],"recId":"647301024","type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reactionAdvanced energy materials","note":["Gesehen am 5. November 2022"]}],"physDesc":[{"extent":"11 S."}],"id":{"eki":["1693190214"],"doi":["10.1002/aenm.201702965"]},"origin":[{"dateIssuedDisp":"30 January 2018","dateIssuedKey":"2018"}],"name":{"displayForm":["David McAteer, Ian J. Godwin, Zheng Ling, Andrew Harvey, Lily He, Conor S. Boland, Victor Vega‐Mayoral, Beata Szydłowska, Aurélie A. Rovetta, Claudia Backes, John B. Boland, Xin Chen, Michael E. G. Lyons, and Jonathan N. Coleman"]},"language":["eng"],"recId":"1693190214","type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Im Titel ist die Zahl \"2\" tiefer gestellt","Gesehen am 24.03.2020"],"title":[{"title_sort":"Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction","title":"Liquid exfoliated Co(OH)2 nanosheets as low-cost, yet high-performance, catalysts for the oxygen evolution reaction"}],"person":[{"role":"aut","display":"McAteer, David","roleDisplay":"VerfasserIn","given":"David","family":"McAteer"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Godwin, Ian J.","given":"Ian J.","family":"Godwin"},{"role":"aut","display":"Ling, Zheng","roleDisplay":"VerfasserIn","given":"Zheng","family":"Ling"},{"family":"Harvey","given":"Andrew","display":"Harvey, Andrew","roleDisplay":"VerfasserIn","role":"aut"},{"family":"He","given":"Lily","roleDisplay":"VerfasserIn","display":"He, Lily","role":"aut"},{"role":"aut","display":"Boland, Conor S.","roleDisplay":"VerfasserIn","given":"Conor S.","family":"Boland"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Vega‐Mayoral, Victor","given":"Victor","family":"Vega‐Mayoral"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Szydłowska, Beata","given":"Beata","family":"Szydłowska"},{"given":"Aurélie A.","family":"Rovetta","role":"aut","display":"Rovetta, Aurélie A.","roleDisplay":"VerfasserIn"},{"family":"Backes","given":"Claudia","roleDisplay":"VerfasserIn","display":"Backes, Claudia","role":"aut"},{"role":"aut","display":"Boland, John B.","roleDisplay":"VerfasserIn","given":"John B.","family":"Boland"},{"given":"Xin","family":"Chen","role":"aut","roleDisplay":"VerfasserIn","display":"Chen, Xin"},{"display":"Lyons, Michael E. G.","roleDisplay":"VerfasserIn","role":"aut","family":"Lyons","given":"Michael E. G."},{"given":"Jonathan N.","family":"Coleman","role":"aut","roleDisplay":"VerfasserIn","display":"Coleman, Jonathan N."}]} | ||
| SRT | |a MCATEERDAVLIQUIDEXFO3020 | ||