Solvent-controlled racemic resolution of C3-symmetric trihydroxytribenzotriquinacenes
A racemic C-3-symmetric trihydroxytribenzotriquinacene was resolved on a large scale by fractional crystallization of the corresponding (1S)-camphanic esters, achieving both enantiopure enantiomers (>99% ee) in 35% and 32% yields. The method relies on a distinct solvent-controlled discrimination...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 28, 2020
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| In: |
The journal of organic chemistry
Year: 2020, Jahrgang: 85, Heft: 5, Pages: 3981-3989 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/acs.joc.9b03410 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.joc.9b03410
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| Verfasserangaben: | Philippe Wagner, Frank Rominger, Thomas Oeser, and Michael Mastalerz |
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