Resistance of amphiphilic polysaccharides against marine fouling organisms

Amphiphilic coatings are promising candidates for fouling-release applications. As hydrophilic components, polysaccharides are interesting and environmentally benign building blocks. We used covalently coupled alginic acid (AA) and hyaluronic acid (HA) and postmodified them with a hydrophobic fluori...

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Hauptverfasser: Bauer, Stella (VerfasserIn) , Alles, Maria (VerfasserIn) , Arpa Sancet, Maria Pilar (VerfasserIn) , Ralston, E. (VerfasserIn) , Swain, G. W. (VerfasserIn) , Aldred, N. (VerfasserIn) , Clare, A. S. (VerfasserIn) , Finlay, J. A. (VerfasserIn) , Callow, M. E. (VerfasserIn) , Callow, J. A. (VerfasserIn) , Rosenhahn, Axel (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: January 15, 2016
In: Biomacromolecules
Year: 2016, Jahrgang: 17, Heft: 3, Pages: 897-904
ISSN:1526-4602
DOI:10.1021/acs.biomac.5b01590
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.biomac.5b01590
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Verfasserangaben:S. Bauer, M. Alles, M.P. Arpa-Sancet, E. Ralston, G.W. Swain, N. Aldred, A.S. Clare, J.A. Finlay, M.E. Callow, J.A. Callow, and A. Rosenhahn

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520 |a Amphiphilic coatings are promising candidates for fouling-release applications. As hydrophilic components, polysaccharides are interesting and environmentally benign building blocks. We used covalently coupled alginic acid (AA) and hyaluronic acid (HA) and postmodified them with a hydrophobic fluorinated amine. The surfaces showed good stability under marine conditions and fluorination led to a decreased uptake of Ca2+ ions after modification. In single species settlement assays (bacteria, diatoms, barnacle cypris larvae), the modification decreased the settlement density and/or the adhesion strength of many of the tested species. Field studies supported findings of the laboratory experiments, as hydrophobic modification of AA and HA decreased diatom colonization. 
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