Solvent control of ligand-metal electron transfer in mononuclear copper complexes with redox-active bisguanidine ligands: this article is dedicated to Prof. Dr. Peter Comba on the occasion of his 65th birthday
Intramolecular electron transfer (IET) processes between the metal and a redox-active ligand in a transition-metal complex are currently intensively studied, as they represent key steps of some redox-catalytic reactions in synthetic chemistry and of some enzymatic redox reactions in biological syste...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
19 June 2018
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| In: |
European journal of inorganic chemistry
Year: 2018, Heft: 32, Pages: 3660-3667 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201800525 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.201800525 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800525 
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| Verfasserangaben: | David F. Schrempp, Elisabeth Kaifer, and Hans-Jörg Himmel |
MARC
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| 520 | |a Intramolecular electron transfer (IET) processes between the metal and a redox-active ligand in a transition-metal complex are currently intensively studied, as they represent key steps of some redox-catalytic reactions in synthetic chemistry and of some enzymatic redox reactions in biological systems. Using a combination of experimental results and quantum chemical calculations, we herein examine in detail the role of the solvent polarity and seemingly small modifications at the redox-active ligand on IET processes in mononuclear copper complexes with redox-active bisguanidine ligands. A direct and simple correlation between the coordination mode and the electronic structure in these complexes is established, assisting in the fine-tuning of the ligand properties for optimal promotion of IET. | ||
| 650 | 4 | |a Coordination chemistry | |
| 650 | 4 | |a Copper | |
| 650 | 4 | |a Electron transfer | |
| 650 | 4 | |a Redox-active ligands | |
| 650 | 4 | |a Valence tautomerism | |
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