Detection of polydimethylsiloxanes transferred from silicone-coated parchment paper to baked goods using direct analysis in real time mass spectrometry
The non-stick properties of parchment papers are achieved by polydimethylsiloxane (PDMS) coatings. During baking, PDMS can thus be extracted from the silicone-coated parchment into the baked goods. Positive-ion direct analysis in real time (DART) mass spectrometry (MS) is highly efficient for the an...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
11 March 2016
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| In: |
Journal of mass spectrometry
Year: 2016, Volume: 51, Issue: 4, Pages: 298-304 |
| ISSN: | 1096-9888 |
| DOI: | 10.1002/jms.3757 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/jms.3757 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/jms.3757 |
| Author Notes: | Andreas Jakob, Elizabeth A. Crawford, Jürgen H. Gross |
| Summary: | The non-stick properties of parchment papers are achieved by polydimethylsiloxane (PDMS) coatings. During baking, PDMS can thus be extracted from the silicone-coated parchment into the baked goods. Positive-ion direct analysis in real time (DART) mass spectrometry (MS) is highly efficient for the analysis of PDMS. A DART-SVP source was coupled to a quadrupole-time-of-flight mass spectrometer to detect PDMS on the contact surface of baked goods after use of silicone-coated parchment papers. DART spectra from the bottom surface of baked cookies and pizzas exhibited signals because of PDMS ions of the general formula [(C2H6SiO)n + NH4]+ in the m/z 800-1900 range. Copyright © 2016 John Wiley & Sons, Ltd. |
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| Item Description: | Gesehen am 30.04.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1096-9888 |
| DOI: | 10.1002/jms.3757 |