Buchumschlag

A versatile hard-soft N/S-ligand for metal coordination and cluster formation

Deprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22−, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22− ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Benson, Callum (VerfasserIn) , Plajer, Alex (VerfasserIn) , García-Rodríguez, Raúl (VerfasserIn) , Bond, Andrew D. (VerfasserIn) , Singh, Sanjay (VerfasserIn) , Gade, Lutz H. (VerfasserIn) , Wright, Dominic S. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 06 Jul 2016
In: Chemical communications
Year: 2016, Jahrgang: 52, Heft: 62, Pages: 9683-9686
ISSN:1364-548X
DOI:10.1039/C6CC04805F
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C6CC04805F
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04805f
Volltext
Verfasserangaben:Callum G. M. Benson, Alex J. Plajer, Raúl García-Rodríguez, Andrew D. Bond, Sanjay Singh, Lutz H. Gade, and Dominic S. Wright

MARC

LEADER 00000caa a2200000 c 4500
001 1697302386
003 DE-627
005 20230428022042.0
007 cr uuu---uuuuu
008 200506s2016 xx |||||o 00| ||eng c
024 7 |a 10.1039/C6CC04805F  |2 doi 
035 |a (DE-627)1697302386 
035 |a (DE-599)KXP1697302386 
035 |a (OCoLC)1341318776 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Benson, Callum  |e VerfasserIn  |0 (DE-588)1208310410  |0 (DE-627)1694559157  |4 aut 
245 1 2 |a A versatile hard-soft N/S-ligand for metal coordination and cluster formation  |c Callum G. M. Benson, Alex J. Plajer, Raúl García-Rodríguez, Andrew D. Bond, Sanjay Singh, Lutz H. Gade, and Dominic S. Wright 
264 1 |c  06 Jul 2016 
300 |a 4 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 06.05.2020 
520 |a Deprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22−, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22− ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures. 
700 1 |a Plajer, Alex  |e VerfasserIn  |0 (DE-588)1160537194  |0 (DE-627)102380719X  |0 (DE-576)505981157  |4 aut 
700 1 |a García-Rodríguez, Raúl  |e VerfasserIn  |4 aut 
700 1 |a Bond, Andrew D.  |e VerfasserIn  |0 (DE-588)1147173974  |0 (DE-627)1008534889  |0 (DE-576)421103493  |4 aut 
700 1 |a Singh, Sanjay  |d 1980-  |e VerfasserIn  |0 (DE-588)1160451915  |0 (DE-627)1023625091  |0 (DE-576)505898837  |4 aut 
700 1 |a Gade, Lutz H.  |d 1963-  |e VerfasserIn  |0 (DE-588)1019812737  |0 (DE-627)691026750  |0 (DE-576)358881870  |4 aut 
700 1 |a Wright, Dominic S.  |e VerfasserIn  |4 aut 
773 0 8 |i Enthalten in  |t Chemical communications  |d Cambridge : Soc., 1965  |g 52(2016), 62, Seite 9683-9686  |h Online-Ressource  |w (DE-627)268759081  |w (DE-600)1472881-3  |w (DE-576)077609867  |x 1364-548X  |7 nnas  |a A versatile hard-soft N/S-ligand for metal coordination and cluster formation 
773 1 8 |g volume:52  |g year:2016  |g number:62  |g pages:9683-9686  |g extent:4  |a A versatile hard-soft N/S-ligand for metal coordination and cluster formation 
856 4 0 |u https://doi.org/10.1039/C6CC04805F  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04805f  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20200506 
993 |a Article 
994 |a 2016 
998 |g 1019812737  |a Gade, Lutz H.  |m 1019812737:Gade, Lutz H.  |d 120000  |d 120200  |e 120000PG1019812737  |e 120200PG1019812737  |k 0/120000/  |k 1/120000/120200/  |p 6 
999 |a KXP-PPN1697302386  |e 3660934879 
BIB |a Y 
SER |a journal 
JSO |a {"recId":"1697302386","relHost":[{"language":["eng"],"name":{"displayForm":["The Royal Society of Chemistry"]},"id":{"issn":["1364-548X"],"zdb":["1472881-3"],"eki":["268759081"]},"note":["Gesehen am 20.02.24"],"origin":[{"dateIssuedKey":"1965","publisher":"Soc. ; Soc.","dateIssuedDisp":"1965-","publisherPlace":"Cambridge ; London"}],"pubHistory":["1965 - 1968; 1996 -"],"recId":"268759081","type":{"media":"Online-Ressource","bibl":"periodical"},"part":{"extent":"4","volume":"52","issue":"62","pages":"9683-9686","year":"2016","text":"52(2016), 62, Seite 9683-9686"},"title":[{"title":"Chemical communications","subtitle":"ChemComm","title_sort":"Chemical communications"}],"disp":"A versatile hard-soft N/S-ligand for metal coordination and cluster formationChemical communications","physDesc":[{"extent":"Online-Ressource"}],"corporate":[{"display":"Royal Society of Chemistry","role":"isb"}],"titleAlt":[{"title":"ChemComm online"},{"title":"Chemical communications online"}]}],"note":["Gesehen am 06.05.2020"],"origin":[{"dateIssuedKey":"2016","dateIssuedDisp":" 06 Jul 2016"}],"title":[{"title":"A versatile hard-soft N/S-ligand for metal coordination and cluster formation","title_sort":"versatile hard-soft N/S-ligand for metal coordination and cluster formation"}],"person":[{"family":"Benson","role":"aut","given":"Callum","display":"Benson, Callum"},{"family":"Plajer","display":"Plajer, Alex","given":"Alex","role":"aut"},{"family":"García-Rodríguez","role":"aut","display":"García-Rodríguez, Raúl","given":"Raúl"},{"display":"Bond, Andrew D.","given":"Andrew D.","role":"aut","family":"Bond"},{"family":"Singh","given":"Sanjay","display":"Singh, Sanjay","role":"aut"},{"family":"Gade","role":"aut","given":"Lutz H.","display":"Gade, Lutz H."},{"family":"Wright","display":"Wright, Dominic S.","given":"Dominic S.","role":"aut"}],"id":{"eki":["1697302386"],"doi":["10.1039/C6CC04805F"]},"physDesc":[{"extent":"4 S."}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"language":["eng"],"name":{"displayForm":["Callum G. M. Benson, Alex J. Plajer, Raúl García-Rodríguez, Andrew D. Bond, Sanjay Singh, Lutz H. Gade, and Dominic S. Wright"]}} 
SRT |a BENSONCALLVERSATILEH0620 

Ähnliche Einträge