Buchumschlag

Coronene-containing N-heteroarenes: 13 rings in a row

We describe the modular synthesis of three novel large N-heteroarenes, containing 9, 11, and 13 annulated rings. This modular system features fused azaacene units to a coronene nucleus. We evaluate the optical and electronic properties and the solid-state packing of the targets. The electronic prope...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Endres, Alexander H. (VerfasserIn) , Schaffroth, Manuel (VerfasserIn) , Paulus, Fabian (VerfasserIn) , Reiß, Hilmar (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Rominger, Frank (VerfasserIn) , Krämer, Roland (VerfasserIn) , Bunz, Uwe H. F. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: January 25, 2016
In: Journal of the American Chemical Society
Year: 2016, Jahrgang: 138, Heft: 6, Pages: 1792-1795
ISSN:1520-5126
DOI:10.1021/jacs.5b12642
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.5b12642
Volltext
Verfasserangaben:Alexander H. Endres, Manuel Schaffroth, Fabian Paulus, Hilmar Reiss, Hubert Wadepohl, Frank Rominger, Roland Krämer, and Uwe H.F. Bunz
Beschreibung
Zusammenfassung:We describe the modular synthesis of three novel large N-heteroarenes, containing 9, 11, and 13 annulated rings. This modular system features fused azaacene units to a coronene nucleus. We evaluate the optical and electronic properties and the solid-state packing of the targets. The electronic properties of the 13-ring N-heteroarene allow the fabrication of a proof-of-concept thin-film transistor. Electron mobilities up to 8 × 10-4 cm/(V s) were obtained for polycrystalline films.
Beschreibung:Gesehen am 07.05.2020
Beschreibung:Online Resource
ISSN:1520-5126
DOI:10.1021/jacs.5b12642

Ähnliche Einträge