Photoionization dynamics of cis-dichloroethene from investigation of vibrationally resolved photoelectron spectra and angular distributions

The influence of vibronic coupling on the outer valence ionic states of cis-dichloroethene has been investigated by recording photoelectron spectra over the excitation range 19-90 eV using plane polarized synchrotron radiation, for two polarization orientations. The photoelectron anisotropy paramete...

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Bibliographic Details
Main Authors: Powis, Ivan (Author) , Gromov, Evgeniy (Author)
Format: Article (Journal)
Language:English
Published: 20 August 2018
In: The journal of chemical physics
Year: 2018, Volume: 149, Issue: 7
ISSN:1089-7690
DOI:10.1063/1.5042216
Online Access:Verlag, Volltext: https://doi.org/10.1063/1.5042216
Verlag: https://aip.scitation.org/doi/10.1063/1.5042216
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Author Notes:I. Powis, R.C. Menzies, D.M.P. Holland, A.B. Trofimov, A.D. Skitnevskaya, E.V. Gromov, E. Antonsson, M. Patanen, C. Nicolas, and C. Miron
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Summary:The influence of vibronic coupling on the outer valence ionic states of cis-dichloroethene has been investigated by recording photoelectron spectra over the excitation range 19-90 eV using plane polarized synchrotron radiation, for two polarization orientations. The photoelectron anisotropy parameters and electronic state branching ratios derived from these spectra have been compared to theoretical predictions obtained with the continuum multiple scattering approach.
Item Description:Gesehen am 11.05.2020
Physical Description:Online Resource
ISSN:1089-7690
DOI:10.1063/1.5042216