Photoionization dynamics of cis-dichloroethene from investigation of vibrationally resolved photoelectron spectra and angular distributions
The influence of vibronic coupling on the outer valence ionic states of cis-dichloroethene has been investigated by recording photoelectron spectra over the excitation range 19-90 eV using plane polarized synchrotron radiation, for two polarization orientations. The photoelectron anisotropy paramete...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
20 August 2018
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| In: |
The journal of chemical physics
Year: 2018, Volume: 149, Issue: 7 |
| ISSN: | 1089-7690 |
| DOI: | 10.1063/1.5042216 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1063/1.5042216 Verlag: https://aip.scitation.org/doi/10.1063/1.5042216 |
| Author Notes: | I. Powis, R.C. Menzies, D.M.P. Holland, A.B. Trofimov, A.D. Skitnevskaya, E.V. Gromov, E. Antonsson, M. Patanen, C. Nicolas, and C. Miron |
| Summary: | The influence of vibronic coupling on the outer valence ionic states of cis-dichloroethene has been investigated by recording photoelectron spectra over the excitation range 19-90 eV using plane polarized synchrotron radiation, for two polarization orientations. The photoelectron anisotropy parameters and electronic state branching ratios derived from these spectra have been compared to theoretical predictions obtained with the continuum multiple scattering approach. |
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| Item Description: | Gesehen am 11.05.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1089-7690 |
| DOI: | 10.1063/1.5042216 |